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223891

Sigma-Aldrich

Bismuth(III) oxide

ReagentPlus®, powder, 10 μm, 99.9% trace metals basis

Sinônimo(s):

Dibismuth trioxide

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About This Item

Fórmula empírica (Notação de Hill):
Bi2O3
Número CAS:
Peso molecular:
465.96
Número CE:
Número MDL:
Código UNSPSC:
12352103
ID de substância PubChem:
NACRES:
NA.23

linha de produto

ReagentPlus®

Ensaio

99.9% trace metals basis

forma

powder

adequação da reação

reagent type: catalyst
core: bismuth

tamanho de partícula

10 μm

cadeia de caracteres SMILES

O=[Bi]O[Bi]=O

InChI

1S/2Bi.3O

chave InChI

WMWLMWRWZQELOS-UHFFFAOYSA-N

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Descrição geral

Bismuth (III) oxide is a yellow, monoclinic crystalline powder. It is insoluble in water and hydroxide solutions but dissolves in acids to form bismuth (III) salts. It can be prepared by heating bismuth in air or by heating hydroxides, carbonates or nitrates of bismuth.

Aplicação

General applications of bismuth (III) oxide are:production of optical glasses with high indices of refraction, precursor in the production of other bismuth compounds.
Bismuth (III) oxide is suitable for dental materials to render them opaque to X-rays.
It is used for the synthesis of pure BiFeO3 perovskite nanoparticles, lead free piezoelectric 0.96(Bi0.5Na0.5)TiO3 - 0.04 BaTiO3.

Características e benefícios

Preparation of new stabilized, oxide ion-conducting, bismuth vanadate phases by a microwave assisted method, from V2O5, Bi2O3 and other solid oxides, was reported. These ceramics show promise in solid oxide fuel cells, water-vapor electrolyzers and oxygen sensors.

Informações legais

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

nwg

Equipamento de proteção individual

dust mask type N95 (US), Eyeshields, Gloves


Certificados de análise (COA)

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Direct mechanosynthesis of pure BiFeO 3 perovskite nanoparticles: reaction mechanism.
Perejon A, et al.
Journal of Material Chemistry C, 1(22), 3551-3562 (2013)
Vaidyanathan, B. et al.
Chemistry of Materials, 10, 3400-3400 (1998)
Rifath Sharmin et al.
Journal of the Air & Waste Management Association (1995), 62(9), 1032-1039 (2012-10-02)
Photocatalytic oxidation (PCO) is a promising technology for indoor air purification due to low operating cost, potentially long service life, and low maintenance. Ultraviolet light-emitting diode (UVLED) is a new concept in the field of PCO, which has several advantages
Arun Prakash Periasamy et al.
Talanta, 87, 15-23 (2011-11-22)
In this work, preparation and characterization of a novel nanocomposite containing bismuth oxide (Bi(2)O(3)) nanoparticles and multiwalled carbon nanotubes (MWCNTs) was presented. Powder X-ray diffraction (XRD) studies revealed that as-synthesized Bi(2)O(3) nanoparticles are crystalline and belong to α-phase with monoclinic
S Sanghi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 83(1), 94-99 (2011-09-06)
Glasses with composition 20CdO·xBi(2)O(3)·(79.5-x)B(2)O(3) (15≤x≤35, x in mol%) containing 0.5 mol% of Er(3+) ions were prepared by melt-quench technique (1150°C in air). The amorphous nature of the glasses was confirmed by X-ray diffraction. The spectroscopic properties of the glasses were

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