189316
3-Chloro-2,2-dimethyl-1-propanol
99%
Sinônimo(s):
2-Chloromethyl-2-methyl-1-propanol
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About This Item
Produtos recomendados
Nível de qualidade
Ensaio
99%
índice de refração
n20/D 1.45 (lit.)
p.e.
87 °C/35 mmHg (lit.)
pf
34-36 °C (lit.)
grupo funcional
chloro
hydroxyl
cadeia de caracteres SMILES
CC(C)(CO)CCl
InChI
1S/C5H11ClO/c1-5(2,3-6)4-7/h7H,3-4H2,1-2H3
chave InChI
CAZPRAORHCOIHC-UHFFFAOYSA-N
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Descrição geral
3-Chloro-2,2-dimethyl-1-propanol undergoes oxidation with pyridinium chlorochromate to yield 3-chloro-2,2-dimethylpropanal which spontaneously trimerizes to s-trioxane.
Aplicação
3-Chloro-2,2-dimethyl-1-propanol has been used in combinatorial preparation of new aroma-impact compounds such as polyfunctional thiols.
Código de classe de armazenamento
10 - Combustible liquids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
159.8 °F - closed cup
Ponto de fulgor (°C)
71 °C - closed cup
Equipamento de proteção individual
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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2, 4, 6-Tri (2'-chloro-1', 1'-dimethylethyl)-s-trioxane: Synthesis, Spectroscopy and Crystal Structure.
Journal of Chemical Crystallography, 40(2), 126-129 (2010)
Combinatorial chemistry & high throughput screening, 9(8), 583-590 (2006-10-05)
Combinatorial chemistry was shown to be an efficient tool for the preparation of new aroma-impact compounds. In this case, polyfunctional thiols were synthesized quickly using halide reagents or Bunte salt intermediates. They were separated by gas chromatography and then characterized
Royal Society open science, 5(5), 180156-180156 (2018-06-13)
A novel alkyl lithium-based initiator with relatively large steric hindrance, tert-butyldimethylsiloxydimethylpropyl lithium (TBDMSODPrLi), was designed and synthesized. By using TBDMSODPrLi, hydroxyl-terminated polybutadiene (HTPB) was prepared via anionic polymerization. The macromolecular structure of HTPB was characterized and verified by FTIR and
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