186317
N,N-Diethylformamide
99%
Sinônimo(s):
N-Formyldiethylamine
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About This Item
Produtos recomendados
Nível de qualidade
Ensaio
99%
forma
liquid
índice de refração
n20/D 1.434 (lit.)
pb
176-177 °C (lit.)
densidade
0.908 g/mL at 25 °C (lit.)
cadeia de caracteres SMILES
CCN(CC)C=O
InChI
1S/C5H11NO/c1-3-6(4-2)5-7/h5H,3-4H2,1-2H3
chave InChI
SUAKHGWARZSWIH-UHFFFAOYSA-N
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Descrição geral
N,N-Diethylformamide undergoes condensation with aromatic o-aminonitriles in the presence of ZnCl2 in sealed reactor to yield quinazoline-2,4(1H,3H)-dione.
Aplicação
N,N-Diethylformamide was used in the synthesis of metal-organic frameworks. It was also used as solvent in the synthesis of porous cubic-shaped ZnO particles.
Palavra indicadora
Warning
Frases de perigo
Declarações de precaução
Classificações de perigo
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
Órgãos-alvo
Respiratory system
Classe de risco de água (WGK)
WGK 1
Equipamento de proteção individual
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Organic letters, 11(6), 1193-1196 (2009-02-26)
A new and facile preparation of quinazoline-2,4(1H,3H)-diones was first reported which was the condensation of aromatic o-aminonitriles with DMF or N,N-diethylformamide in the presence of ZnCl(2) (0.5-10 mol %) at 190-200 degrees C in the sealed reactor.
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