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186317

Sigma-Aldrich

N,N-Diethylformamide

99%

Sinônimo(s):

N-Formyldiethylamine

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About This Item

Fórmula linear:
HCON(C2H5)2
Número CAS:
617-84-5
Peso molecular:
101.15
Beilstein:
1209392
Número CE:
210-533-2
Número MDL:
MFCD00003287
Código UNSPSC:
12352100
ID de substância PubChem:
24851213
NACRES:
NA.22

Ensaio

99%

forma

liquid

índice de refração

n20/D 1.434 (lit.)

pb

176-177 °C (lit.)

densidade

0.908 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

CCN(CC)C=O

InChI

1S/C5H11NO/c1-3-6(4-2)5-7/h5H,3-4H2,1-2H3

chave InChI

SUAKHGWARZSWIH-UHFFFAOYSA-N

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Descrição geral

N,N-Diethylformamide undergoes condensation with aromatic o-aminonitriles in the presence of ZnCl2 in sealed reactor to yield quinazoline-2,4(1H,3H)-dione.

Aplicação

N,N-Diethylformamide was used in the synthesis of metal-organic frameworks. It was also used as solvent in the synthesis of porous cubic-shaped ZnO particles.

Pictogramas

FlameExclamation mark
GHS02,GHS07

Palavra indicadora

Warning

Frases de perigo

H226,H315,H319,H335

Classificações de perigo

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Órgãos-alvo

Respiratory system

Classe de risco de água (WGK)

WGK 1

Equipamento de proteção individual

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análise (COA)

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Yingmu Zhang et al.
Dalton transactions (Cambridge, England : 2003), 47(34), 11806-11811 (2018-06-05)
A new luminescent mesoporous metal-organic framework (PCN-604) was successfully synthesized from trimetric clusters, Al3(O)(CH3COO)6, and pyridine-based tritopic linkers, 4,4',4''-(pyridine-2,4,6-triyl)tribenzoate (PTB), via a solvothermal reaction. The MOF with an MTN topology possesses remarkable aqueous and thermal stabilities. Due to the efficient
Yu Kimitsuka et al.
Inorganic chemistry, 52(24), 14028-14033 (2013-11-26)
A method for synthesizing porous cubic-shaped ZnO particles a few tens of micrometers in size is described on the basis of a pyrolytic conversion of Zn-terephthalate metal-organic frameworks (MOFs). MOF crystals were initially grown in solutions containing Zn(NO3)2·6H2O and terephthalic
Yuxia Shen et al.
Advanced materials (Deerfield Beach, Fla.), 30(52), e1802497-e1802497 (2018-11-06)
Large-scale synthesis of van der Waals (vdW) metal-organic framework (MOF) nanosheets with controlled crystallinity and interlayer coupling strength is one of the bottlenecks in 2D materials that has limited its successful transition to large-scale applications. Here, scalable synthesis of mBDC
Jiarong Li et al.
Organic letters, 11(6), 1193-1196 (2009-02-26)
A new and facile preparation of quinazoline-2,4(1H,3H)-diones was first reported which was the condensation of aromatic o-aminonitriles with DMF or N,N-diethylformamide in the presence of ZnCl(2) (0.5-10 mol %) at 190-200 degrees C in the sealed reactor.
South African research into AIDS "cure" severely criticised.
P Sidley
BMJ (Clinical research ed.), 314(7083), 771-771 (1997-03-15)
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