254274
Lithium hydroxide monohydrate
99.95% trace metals basis
Synonym(s):
Lithine hydrate
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All Photos(4)
About This Item
Linear Formula:
LiOH · H2O
CAS Number:
Molecular Weight:
41.96
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
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Quality Level
assay
99.95% trace metals basis
form
crystalline
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impurities
≤550.0 ppm Trace Metal Analysis
application(s)
battery manufacturing
greener alternative category
SMILES string
[Li+].O.[OH-]
InChI
1S/Li.2H2O/h;2*1H2/q+1;;/p-1
InChI key
GLXDVVHUTZTUQK-UHFFFAOYSA-M
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General description
Lithium hydroxide monohydrate is a strongly alkaline crystalline solid soluble in water. It is prepared industrially by recovering it from spodumene or by evaporating a solution prepared by reacting calcium hydroxide and lithium carbonate. It is mainly used in the synthesis of cathode materials for lithium-ion batteries, such as lithium cobalt oxide (LiCoO2) and lithium iron phosphate. It is also preferred over lithium carbonate for producing lithium nickel manganese cobalt oxides.
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Application
Lithium hydroxide monohydrate can be used mainly for the synthesis of cathode materials for Lithium-ion batteries:
- To synthesize Olivine LiFePO4 nanoplates with different crystal orientations by glycol-based solvothermal process. It demonstrated that the crystal orientation of cathode nanoplates plays an important role in the performance.
- As a precursor for the synthesis of LiFePO4 platelets under hydrothermal synthesis conditions. It exhibited homogeneous particle size distribution, greater electrochemical performances and cycle life, and morphology control.
- To synthesize Ni-rich Li[NixCoyMn1–x–y]O2 gradient cathodes (NCM). These cathodes exhibited enhanced cycling and chemical stability due to their strong crystallographic texture, unique particle morphology, and highly correlated particle orientation.
- As a precursor to prepare porous salt hydrate-based composites for low-temperature thermochemical heat storage.
- As an electrolyte additive in lithium-ion batteries.
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Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
Storage Class
8B - Non-combustible corrosive hazardous materials
wgk_germany
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Articles
Lithium-ion batteries represent a group of electrochemical devices used for electricity storage and have attracted a lot of attention in the past two decades due to their portability, rechargeability and low cost.
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