900258

Isopropoxy(phenyl)silane

• Synonim(y): RubenSilane
• Wzór empiryczny (zapis Hilla): C₉H₁₄OSi
• Numer CAS: 910037-63-7
• Masa cząsteczkowa: 166.29
• Numer MDL: MFCD31707672
• Kod UNSPSC: 12352005
• NACRES: NA.22

Właściwości

• Formularz: liquid
• Poziom jakości: 100
• przydatność reakcji: reagent type: reductant; reaction type: Reductions
• współczynnik refrakcji: n/D 1.4799
• gęstość: 0.926 g/mL
• temp. przechowywania: 2-8°C
• ciąg SMILES: [SiH2](OC(C)C)c1ccccc1
• InChI: 1S/C9H14OSi/c1-8(2)10-11-9-6-4-3-5-7-9/h3-8H,11H2,1-2H3
• Klucz InChI: XYMAHMLQCLMTDN-UHFFFAOYSA-N

Opis

Opis ogólny

Isopropoxy(phenyl)silane is used as a stoichiometric reductant that allows for a significant decrease in catalyst loading, lower reaction temperatures, a wide range of functional group tolerance, and more diverse solvents in metal-catalyzed Mukaiyama hydrofunctionalizations.

Zastosowanie

Isopropoxy(phenyl)silane can be used as a hydride source for alkene hydrofunctionalization reactions in the presence of metal catalysts, particularly under aprotic, nonalcoholic conditions. This reagent is considered as one of the most efficient stoichiometric reductants than phenylsilane because of its ability to exclude alcohol solvent from a series of catalytic reactions. When utilized, it allows the researcher to significantly decrease catalyst loadings, lower reaction temperatures, and employ more diverse solvents in iron- and manganese-catalyzed Mukaiyama hydrofunctionalizations.
It can be used as a reagent in:

• The hydrogenation of olefins
• Branch-selective olefin cross-coupling reactions
• Markovnikov alkene hydration/amination reactions

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Informacja o środkach bezpieczeństwa

• Kod klasy składowania: 10 - Combustible liquids
• Klasa zagrożenia wodnego (WGK): WGK 3