371343

4-Hydroxy-TEMPO benzoate, free radical

97%

• Synonim(y): 4-Hydroxy-TEMPO benzoate, 4-Hydroxy-2,2,6,6-tetramethylpiperidine 1-oxyl benzoate
• Wzór empiryczny (zapis Hilla): C₁₆H₂₂NO₃
• Numer CAS: 3225-26-1
• Masa cząsteczkowa: 276.35
• Beilstein: 1431263
• Numer MDL: MFCD00075563
• Kod UNSPSC: 12352000
• Identyfikator substancji w PubChem: 24863101
• NACRES: NA.22

Właściwości

• Próba: 97%
• Postać: solid
• mp: 99-101 °C (lit.)
• grupa funkcyjna: ester; phenyl
• ciąg SMILES: CC1(C)CC(CC(C)(C)N1[O])OC(=O)c2ccccc2
• InChI: 1S/C16H22NO3/c1-15(2)10-13(11-16(3,4)17(15)19)20-14(18)12-8-6-5-7-9-12/h5-9,13H,10-11H2,1-4H3
• Klucz InChI: MJEDTBDGYVATPI-UHFFFAOYSA-N

Opis

Opis ogólny

4-Hydroxy-TEMPO benzoate is a 4-substituted 2,2,6,6-tetramethylpiperidyl-1-oxy (TEMPO) derivative.

Zastosowanie

4-Hydroxy-TEMPO benzoate was employed as spin probe to investigate the mechanism of synthesis of SBA-15 and to evaluate its surface properties and pore structure by electron paramagnetic resonance spectroscopy (EPR). It was also used for the functionalization of various polydienes (polybutadiene and polyisoprene). Functionalized polydienes were analyzed by gel permeation chromatography.

Recycling catalyst in hypochlorite/bromite-nitroxide oxidizing system for conversion of alcohols to aldehydes, ketones, and carboxylic acids. It circumvents the need to use a catalytic or stoichiometric heavy metal oxidant.

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Informacja o środkach bezpieczeństwa

• Kod klasy składowania: 11 - Combustible Solids
• Klasa zagrożenia wodnego (WGK): WGK 3
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable
• Środki ochrony indywidualnej: Eyeshields, Gloves, type N95 (US)