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19670
4-tert-Butylcatechol
≥97.0% (HPLC)
Synonim(y):
4-(1,1-dimetyloetylo)benzeno-1,2-diol, 4-TBC, 4-tert-butylokatechina, 4-tert-butylopirokatechol, p-tert-butylokatechol
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About This Item
Wzór liniowy:
(CH3)3CC6H3-1,2-(OH)2
Numer CAS:
Masa cząsteczkowa:
166.22
Beilstein:
2043335
Numer WE:
Numer MDL:
Kod UNSPSC:
12352100
Identyfikator substancji w PubChem:
NACRES:
NA.22
Polecane produkty
Poziom jakości
Próba
≥97.0% (HPLC)
bp
285 °C (lit.)
mp
52-55 °C (lit.)
53-58 °C
rozpuszczalność
methanol: soluble 1 g/10 mL, clear, colorless to slightly yellow
ciąg SMILES
CC(C)(C)c1ccc(O)c(O)c1
InChI
1S/C10H14O2/c1-10(2,3)7-4-5-8(11)9(12)6-7/h4-6,11-12H,1-3H3
Klucz InChI
XESZUVZBAMCAEJ-UHFFFAOYSA-N
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Opis ogólny
4-tert-Butylcatechol, in the presence of O2 catalyzed by tyrosinase, yields 4-tert-butyl-o-benzoquinone. Electrochemical oxidation of 4-tert-butylcatechol in the presence of 4-hydroxycoumarin as nucleophile has been studied using cyclic voltammetry and controlled-potential coulometry. It undergoes electrochemical trimerization via anodic oxidation and mechanism of trimerization has been studied using cyclic voltammetry and controlled-potential coulometry.
Zastosowanie
- Electrochemical Oxidation of Catechol and 4-tert-Butylcatechol: This study explores the oxidation reactions of catechol and 4-tert-butylcatechol, detailing the electrochemical pathways and potential applications in synthetic chemistry (E Tammari, M Heravi, D Nematollahi, academia.edu).
- Selective Oxidation of 4-tert-butylphenol by Hydrogen Peroxide: Discusses the catalytic performance of titanosilicates in the selective oxidation to 4-tert-butylcatechol, emphasizing improvements in selectivity and yield (RR Talipova et al., Applied Petrochemical Research, 2016 - Springer).
- Barium 5-(tert-butyl)-2,3-dihydroxybenzenesulfonate: This research presents the sulfonation process of 4-tert-butylcatechol, contributing to the development of new derivatives for advanced materials (LG Rubicheva, DA Lukyanov - Molbank, 2022 - mdpi.com).
- UV-AOPs for Efficient Continuous Flow Removal of 4-tert-butylphenol: Compares various advanced oxidation processes for removing contaminants like 4-tert-butylcatechol from water, highlighting the environmental applications (S Mergenbayeva, SG Poulopoulos - Processes, 2021 - mdpi.com).
- The Study on the Degradation of 4-tert-butylphenol by Hydroxyl Radical: This article investigates the degradation pathways of 4-tert-butylcatechol, providing insights into the environmental impact and degradation mechanisms (YL Wu et al., China Environmental Science, 2016 - cabdirect.org).
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Hasło ostrzegawcze
Danger
Zwroty wskazujące rodzaj zagrożenia
Zwroty wskazujące środki ostrożności
Klasyfikacja zagrożeń
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1
Kod klasy składowania
8A - Combustible corrosive hazardous materials
Klasa zagrożenia wodnego (WGK)
WGK 3
Temperatura zapłonu (°F)
235.4 °F - closed cup
Temperatura zapłonu (°C)
113 °C - closed cup
Środki ochrony indywidualnej
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Electrochemical study of 3, 4-dihydroxybenzoic acid and 4-tert-butylcatechol in the presence of 4-hydroxycoumarin application to the electro-organic synthesis of coumestan derivatives.
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Journal of Electroanalytical Chemistry, 430(1), 141-146 (1997)
Mechanistic study of electrochemical oxidation of 4-tert-butylcatechol: A facile electrochemical method for the synthesis of new trimer of 4-tert-butylcatechol.
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A procedure for calibrating a Clark-type oxygen electrode is described. This method is based on the oxidation of 4-tert-butylcatechol (TBC) by O2 catalyzed by tyrosinase, to yield 4-tert-butyl-o-benzoquinone (TBCQ). This reaction consumes known amounts of oxygen in accordance with the
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4-Tertiary butyl catechol (TBC) causes depigmentation in humans and animals and stimulates formation of pheomelanosomes. In this study, we investigated the effects of noncytotoxic doses of TBC on glutathione S-transferase (GST) activity in the skin of Uscd strain mice and
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