409405

Chlorotris(trimethylsilyl)silane

97%

• 동의어(들): 1,1,1,3,3,3-Hexamethyl-2-(trimethylsilyl)-2-chlorotrisilane, 2-Chloro-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane, Tris(trimethylsilyl)chlorosilane, Tris(trimethylsilyl)silyl chloride
• Linear Formula: [(CH₃)₃Si]₃SiCl
• CAS Number: 5565-32-2
• Molecular Weight: 283.11
• MDL number: MFCD01321222
• UNSPSC 코드: 12352101
• PubChem Substance ID: 24865643
• NACRES: NA.22

속성

• 분석: 97%
• 양식: solid
• mp: 50-52 °C (lit.)
• SMILES string: C[Si](C)(C)[Si](Cl)([Si](C)(C)C)[Si](C)(C)C
• InChI: 1S/C9H27ClSi4/c1-11(2,3)14(10,12(4,5)6)13(7,8)9/h1-9H3
• InChI key: HCOROOJWVHFMRJ-UHFFFAOYSA-N

설명

일반 설명

Chlorotris(trimethylsilyl)silane is an organosilicon reagent, which is generally employed in the protection of alcohols. It is also used to prepare organometallic reagents, silyl enol ethers, and novel polymers/materials.

애플리케이션

Super Silyl Protecting Groups

Used for:

• Insertion into a P-P bond
• Diastereoselective aldol and cascade reactions
• Preparation of hypersilyl substituted monophosphines and diphosphines

안전성 정보

• 픽토그램: GHS02,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H228,H261,H315,H319,H335
• 예방조치 성명서: P210 - P231 + P232 - P240 - P241 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react 3
• 표적 기관: Respiratory system
• 보충제 위험성: EUH029
• Storage Class Code: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flash Point (°F): 87.8 °F - closed cup
• Flash Point (°C): 31 °C - closed cup
• 개인 보호 장비: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges