323136

Trimethylboroxine

99%

• 동의어(들): 2,4,6-Trimethyl-1,3,5,2,4,6-trioxatriborinane, 2,4,6-Trimethylboroxine, Methaneboronic anhydride, Trimethyl-1,3,5,2,4,6-trioxatriborinane
• 실험식(Hill 표기법): C₃H₉B₃O₃
• CAS Number: 823-96-1
• Molecular Weight: 125.53
• Beilstein: 1757008
• MDL number: MFCD00013354
• UNSPSC 코드: 12352103
• PubChem Substance ID: 24859217
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 99%
• 양식: liquid
• refractive index: n20/D 1.362 (lit.)
• bp: 78-80 °C (lit.)
• mp: −38 °C (lit.)
• density: 0.898 g/mL at 25 °C (lit.)
• SMILES string: Cb1ob(C)ob(C)o1
• InChI: 1S/C3H9B3O3/c1-4-7-5(2)9-6(3)8-4/h1-3H3
• InChI key: GBBSAMQTQCPOBF-UHFFFAOYSA-N

설명

애플리케이션

Trimethylboroxine (TMB) is a cyclic anhydride of methyl-boronic acid. It can be been used:

• As a derivatizing agent for gas chromatographic/mass spectrometric analysis.
• In the preparation of methylaluminoxane (MAO) which is used in the polymerization of olefins.
• As an electrolyte additive to enhance the interface stability of electrode/electrolyte.
• In methylation of aryl halides by palladium-catalyzed Suzuki-Miyaura coupling reaction.
• In the preparation of CBS (Corey, Bakshi and Shibata) catalysts for asymmetric reductions of ketones to alcohols.

안전성 정보

• 픽토그램: GHS02,GHS05
• 신호어: Danger
• 유해 및 위험 성명서: H225,H314
• 예방조치 성명서: P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Flam. Liq. 2 - Skin Corr. 1B
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): 15.8 °F - closed cup
• Flash Point (°C): -9 °C - closed cup
• 개인 보호 장비: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter