8.06722

Nickel(II) chloride

anhydrous for synthesis

• 別名: Nickel(II) chloride, Nickel dichloride
• 実験式（ヒル表記法）: Cl₂Ni
• CAS番号: 7718-54-9
• 分子量: 129.60
• UNSPSCコード: 12352302
• EC Index Number: 231-743-0
• NACRES: NA.22
• フォーム: powder

特性

• 蒸気圧: 1.33 hPa ( 671 °C)
• 品質水準: 200
• フォーム: powder
• 有効性: 105 mg/kg LD₅₀, oral (Rat)
• pH: 4 (20 °C, 500 g/L in H₂O)
• mp: 1009 °C
• 密度: 3.55 g/cm³
• 保管温度: 2-30°C
• InChI: 1S/2ClH.Ni/h2*1H;/q;;+2/p-2
• InChI Key: QMMRZOWCJAIUJA-UHFFFAOYSA-L

詳細

アプリケーション

Nickel(II) chloride can be used as a catalyst:

• To synthesize acyclic and cyclic dithioacetals via thioacetalization of aldehydes.
• To prepare α-aminonitrile derivatives via a one-pot, three-component coupling reaction of aldehydes, amines, and trimethylsilyl cyanide.
• In the hydrodefluorination of fluoroarenes in the presence of lithium triethylborohydride.

アナリシスノート

Assay (complexometric): 98.0 - 102.0 %
Loss on drying (150 °C; 3h): ≤ 1.0 %

安全性情報

• ピクトグラム: GHS06,GHS08,GHS09
• シグナルワード: Danger
• 危険有害性情報: H301 + H331 - H315 - H317 - H334 - H341 - H350i - H360D - H372 - H410
• 注意書き: P202 - P273 - P280 - P301 + P310 - P302 + P352 - P304 + P340 + P311
• 危険有害性の分類: Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation
• ターゲットの組織: Lungs
• 保管分類コード: 6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable