804363

Potassium 4-anisoyltrifluoroborate

• 実験式（ヒル表記法）: C₈H₇BF₃KO₂
• CAS番号: 1622923-47-0
• 分子量: 242.04
• UNSPSCコード: 12352103
• PubChem Substance ID: 329768864
• NACRES: NA.22

特性

• 形状: powder
• 品質水準: 100
• SMILES記法: O=C(B(F)(F)F)C1=CC=C(OC)C=C1.[K]
• InChI: 1S/C8H7BF3O2.K.H/c1-14-7-4-2-6(3-5-7)8(13)9(10,11)12;;/h2-5H,1H3;;
• InChI Key: VXVQBCXLJYVTDZ-UHFFFAOYSA-N

詳細

アプリケーション

Acyltrifluroborates (KAT′s) are bench, air, and moisture stable reagents for rapid, chemoselective amide bond formations with hydroxylamines. These amide bond forming reactions proceed under aqueous conditions, without the need for coupling reagents or protecting groups. This product was introduced in collaboration with the Bode Research Group.

その他情報

Amide-Forming Ligation of Acyltrifluoroborates and Hydroxylamines in Water

Rapid Ligations with Equimolar Reactants in Water with the Potassium Acyltrifluoroborate (KAT) Amide Formation

Synthesis of Chemically and Configurationally Stable Monofluoro Acylboronates: Effect of Ligand Structure on their Formation, Properties and Reactivities

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H315 - H319 - H335
• 注意書き: P280 - P304 + P340 + P312 - P305 + P351 + P338 - P337 + P313
• 危険有害性の分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable