761206

4-Pentenylmagnesium bromide solution

0.5 M in THF

• 別名: 4-Pentene-1-magnesium bromide solution
• 実験式（ヒル表記法）: C₅H₉BrMg
• 分子量: 173.33
• MDL番号: MFCD11553331
• UNSPSCコード: 12352302
• PubChem Substance ID: 329766914
• NACRES: NA.22

特性

• 形状: solution
• 品質水準: 100
• 反応適合性: reaction type: Grignard Reaction
• 濃度: 0.5 M in THF
• 密度: 0.940 g/mL at 25 °C
• 官能基: allyl
• SMILES記法: Br[Mg]CCCC=C
• InChI: 1S/C5H9.BrH.Mg/c1-3-5-4-2;;/h3H,1-2,4-5H2;1H;/q;;+1/p-1
• InChI Key: LHTUYNSQNJOCCB-UHFFFAOYSA-M

詳細

アプリケーション

4-Pentenylmagnesium bromide is a general Grignard reagent used in the total synthesis of (−)-sarain A, (−)-salicylihalamide A and (+)-erysotramidine. It is also used in the synthesis of hexa-peri-hexabenzocoronene cyclophane.

安全性情報

• ピクトグラム: GHS02,GHS08,GHS05,GHS07
• シグナルワード: Danger
• 危険有害性情報: H225,H260,H302,H314,H335,H351
• 注意書き: P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
• 危険有害性の分類: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
• ターゲットの組織: Respiratory system
• 補足的ハザード: EUH019
• 保管分類コード: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• 引火点(°F): 11.8 °F - closed cup
• 引火点(℃): -11.2 °C - closed cup