683248

(11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1d:1′,2′-f]-1,3,2-dioxaphosphepin-4-amine

• 実験式（ヒル表記法）: C₄₆H₃₆NO₂P₃
• CAS番号: 913617-04-6
• 分子量: 727.70
• MDL番号: MFCD09750461
• UNSPSCコード: 12352005
• PubChem Substance ID: 24885751
• NACRES: NA.22

特性

• フォーム: solid
• 品質水準: 100
• mp: 245-249 °C
• 官能基: amine; phosphine
• 保管温度: 2-8°C
• SMILES記法: CN(C)P1Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)P(c6ccccc6)c7ccccc7)P(c8ccccc8)c9ccccc9
• InChI: 1S/C46H36NO2P3/c1-47(2)52-48-45-41(50(35-21-7-3-8-22-35)36-23-9-4-10-24-36)31-33-19-15-17-29-39(33)43(45)44-40-30-18-16-20-34(40)32-42(46(44)49-52)51(37-25-11-5-12-26-37)38-27-13-6-14-28-38/h3-32H,1-2H3
• InChI Key: JVTXDRKUFXCFCF-UHFFFAOYSA-N

詳細

アプリケーション

DSM MonoPhos Family of Highly Efficient Privileged Ligands

(11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin-4-amine is a phosphine-phosphoramidite ligand, which can be used in:

• The stereoselective preparation of aminoesters via rhodium-catalyzed enantioselective hydrogenation of dehydroaminoesters.
• The Rh-catalyzed asymmetric hydrogenation of N-(α-arylvinyl) acetamides.

法的情報

Sold under license from DSM for research purposes only.

安全性情報

• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable