594806

ブチルボロン酸 N,N,N',N'-テトラメチル-D-酒石酸 ジアミドエステル

97%

• 別名: (4S,5S)-2-Butyl-N,N,N′N′-tetramethyl-1,3,2-dioxaborolane-4,5-dicarboxamide
• 実験式（ヒル表記法）: C₁₂H₂₃BN₂O₄
• CAS番号: 161344-84-9
• 分子量: 270.13
• MDL番号: MFCD05663838
• UNSPSCコード: 12352103
• PubChem Substance ID: 24881537
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 97%
• 光学活性: [α]20/D +106°, c = 1% in chloroform
• 屈折率: n20/D 1.4780 (lit.)
• bp: 305-306 °C (lit.)
• 密度: 1.096 g/mL at 25 °C (lit.)
• SMILES記法: CCCCB1O[C@@H]([C@H](O1)C(=O)N(C)C)C(=O)N(C)C
• InChI: 1S/C12H23BN2O4/c1-6-7-8-13-18-9(11(16)14(2)3)10(19-13)12(17)15(4)5/h9-10H,6-8H2,1-5H3/t9-,10-/m0/s1
• InChI Key: AFQWQRBBIZKYTE-UWVGGRQHSA-N

詳細

アプリケーション

Butylboronic acid N,N,N′,N′-tetramethyl-D-tartaric acid diamide is a dioxaborolane ligand that can be used to prepare:

• Enantioenriched spiropentanes via zinc catalyzed cyclopropanation of corresponding hydroxymethylallenes.
• 1,2,3-trisubstituted cyclopropane derivatives by asymmetric cyclopropanation of allylic alcohols in the presence of zinc reagents.
• Glycolipids plakosides A, B, and their derivatives by Sharpless asymmetric dihydroxylation and cyclopropanation reaction.

安全性情報

• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): >230.0 °F - closed cup
• 引火点(℃): > 110 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)