526304

Cyanoborohydride, polymer supported

macroporous, 20-50 mesh, extent of labeling: ~2.0-3.5 mmol/g loading

• 別名: Cyanoborohydride on Amberlite^™ IRA-400
• UNSPSCコード: 12352117
• PubChem Substance ID: 329757864
• NACRES: NA.22

特性

• フォーム: macroporous
• 品質水準: 200
• 反応適合性: reaction type: solution phase peptide synthesis; reactivity: imine reactive
• 標識化の程度: ~2.0-3.5 mmol/g loading
• 粒径: 20-50 mesh
• mp: >300 °C (lit.)
• 保管温度: 2-8°C

詳細

詳細

Cyanoborohydride, polymer supported: is a polymer-supported reducing agent used in reductive amination reactions at room temperature.

アプリケーション

Polymer supported cyanoborohydride (PSCBH) has been used in the reductive alkylation aminocyclitols for the preparation of corresponding secondary amines.
It can also be used:

• In combination with manganese dioxide (MnO₂) for one-pot conversion of alcohols to secondary or tertiary amines.
• In the synthesis of natural products, (±)-oxomaritidine and (±)-epimaritidine.

法的情報

Amberlite is a trademark of DuPont de Nemours, Inc.

安全性情報

• 保管分類コード: 11 - Combustible Solids
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): Eyeshields, Gloves, type N95 (US)