419184

Triphenylphosphine diiodide

technical grade, 90%

• 別名: Diiodotriphenylphosphorane
• 化学式: (C₆H₅)₃PI₂
• CAS番号: 6396-07-2
• 分子量: 516.09
• Beilstein: 2740417
• MDL番号: MFCD00216568
• UNSPSCコード: 12352101
• PubChem Substance ID: 24866095
• NACRES: NA.06

特性

• グレード: technical grade
• 品質水準: 100
• アッセイ: 90%
• フォーム: solid
• mp: 210-220 °C (lit.)
• 官能基: phosphine
• SMILES記法: IP(I)(c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C18H15I2P/c19-21(20,16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
• InChI Key: NSWZEXJQHIXCFL-UHFFFAOYSA-N

詳細

アプリケーション

Triphenylphosphine diiodide (Ph₃P. I₂) can be used as a reagent:

• To facilitate the conversion of alcohol, thiol, and enol functional groups into alkyl iodides via formation of alkoxyphosphonium iodide.
• To prepare β-iodo-α,β-unsaturated ketones from cyclic β-diketones in the presence of triethyl amine.
• In the synthesis of alkyl nitrates from alcohols.
• In the Beckmann rearrangement reaction to synthesize lactams from cycloalkanone oxime.
• For the preparation of aromatic and aliphatic carboxylic acid esters in the presence of N,N-dimethylaminopyridine.

Ph₃P. I₂ can also be used to reduce graphene oxide for the production of graphene nanosheets under mild and environmentally friendly conditions.

安全性情報

• ピクトグラム: GHS08,GHS05
• シグナルワード: Danger
• 危険有害性情報: H314,H317,H334,H361fd
• 注意書き: P202 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• 危険有害性の分類: Eye Dam. 1 - Repr. 2 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1
• 保管分類コード: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• 引火点(°F): Not applicable
• 引火点(℃): Not applicable
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges