405752

2-Allylcyclohexanone

97%

• 化学式: H₂C=CHCH₂C₆H₉(=O)
• CAS番号: 94-66-6
• 分子量: 138.21
• EC Number: 202-352-2
• MDL番号: MFCD00043548
• UNSPSCコード: 12352100
• PubChem Substance ID: 24865329
• NACRES: NA.22

特性

• 品質水準: 100
• アッセイ: 97%
• 形状: liquid
• 屈折率: n20/D 1.469 (lit.)
• bp: 94 °C/23 mmHg (lit.)
• 密度: 0.927 g/mL at 25 °C (lit.)
• 官能基: allyl; ketone
• SMILES記法: C=CCC1CCCCC1=O
• InChI: 1S/C9H14O/c1-2-5-8-6-3-4-7-9(8)10/h2,8H,1,3-7H2
• InChI Key: UPGHEUSRLZSXAE-UHFFFAOYSA-N

詳細

詳細

2-Allylcyclohexanone is a β,γ-unsaturated ketone. Selective oxidation of 2-allylcyclohexanone by benzonitrile-hydrogen peroxide has been reported. Asymmetric synthesis of 2-alkylcyclohexanones by alkylation of cyclohexanone enamines (III) of L-proline ester derivatives has been described. Oxidation of 2-allylcyclohexanone by 90% hydrogen peroxide catalyzed by arsonated polystyrene has been studied.

アプリケーション

2-Allylcyclohexanone may be used in the synthesis of the following:

• bicyclo[3.3.1]non-2-en-9-one
• R-(-)-epilachnene, an antipode of the defensive droplets from the Mexican bean beetle, Epilachna varivestis

安全性情報

• ピクトグラム: GHS07
• シグナルワード: Warning
• 危険有害性情報: H302 + H312 + H332,H315,H319,H335
• 注意書き: P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
• 危険有害性の分類: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• ターゲットの組織: Respiratory system
• 保管分類コード: 10 - Combustible liquids
• WGK: WGK 3
• 引火点(°F): 235.4 °F - closed cup
• 引火点(℃): 113 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter