265152

2,6-ジフルオロベンズアルデヒド

98%

• 化学式: F₂C₆H₃CHO
• CAS番号: 437-81-0
• 分子量: 142.10
• Beilstein: 1935273
• MDL番号: MFCD00010293
• UNSPSCコード: 12352100
• PubChem Substance ID: 24856057
• NACRES: NA.22

特性

• アッセイ: 98%
• 形状: liquid
• 屈折率: n20/D 1.502 (lit.)
• bp: 82-84 °C/15 mmHg (lit.)
• mp: 15-17 °C (lit.)
• 密度: 1.317 g/mL at 25 °C (lit.)
• 官能基: aldehyde
• 保管温度: 2-8°C
• SMILES記法: Fc1cccc(F)c1C=O
• InChI: 1S/C7H4F2O/c8-6-2-1-3-7(9)5(6)4-10/h1-4H
• InChI Key: SOWRUJSGHKNOKN-UHFFFAOYSA-N

詳細

アプリケーション

2,6-Difluorobenzaldehyde can be used as a reactant to synthesize:

• 5-Cyano-6-(2,6-difluorophenyl)-5,6-dihydro-2-thiouracil via one-pot cyclocondensation reaction with ethyl cyanoacetate and thiourea.
• 1-(2,6-Difluorobenzyl)-2-(2,6-difluorophenyl)-benzimidazole by reacting with 1,2-phenylenediamine in the presence of a catalytic amount of p-toluenesulfonic acid.
• (3E)-4-(2,6-Difluorophenyl)-3-buten-2-one by Wittig olefination reaction with acetylmethylidenetriphenyl phosphorane.
• Methyl 4-fluorobenzo[b]thiophene-2-carboxylate by treating with methyl thioglycolate in the presence of K₂CO₃.

安全性情報

• ピクトグラム: GHS05
• シグナルワード: Danger
• 危険有害性情報: H314,H412
• 注意書き: P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• 危険有害性の分類: Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1C
• 保管分類コード: 8A - Combustible corrosive hazardous materials
• WGK: WGK 2
• 引火点(°F): 180.5 °F - closed cup
• 引火点(℃): 82.5 °C - closed cup
• 個人用保護具 (PPE): Eyeshields, Gloves, type ABEK (EN14387) respirator filter