C100005
1,3-Cyclohexadiene
contains 0.05% BHT as inhibitor, 97%
Sinonimo/i:
1,2-Dihydrobenzene
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About This Item
Formula empirica (notazione di Hill):
C6H8
Numero CAS:
Peso molecolare:
80.13
Beilstein:
506024
Numero CE:
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22
Stato:
liquid
Saggio:
97%
Prodotti consigliati
Livello qualitativo
Saggio
97%
Stato
liquid
contiene
0.05% BHT as inhibitor
Indice di rifrazione
n20/D 1.474 (lit.)
P. ebollizione
80 °C (lit.)
Densità
0.841 g/mL at 25 °C (lit.)
Temperatura di conservazione
2-8°C
Stringa SMILE
C1CC=CC=C1
InChI
1S/C6H8/c1-2-4-6-5-3-1/h1-4H,5-6H2
MGNZXYYWBUKAII-UHFFFAOYSA-N
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Applicazioni
1,3-Cyclohexadiene can undergo:
- C-C coupling with aromatic alcohols via iridium-catalyzed hydrogen auto-transfer and with aldehydes via transfer hydrogenation mediated by isopropanol to form carbonyl addition products.
- Living anionic polymerization with n-BuLi/TMEDA system to form polycyclohexadiene.
- Platinum-catalyzed silaboration to form (1R,4S)-1-(dimethylphenylsilyl)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-cyclohexene.
- Aerobic palladium-catalyzed 1,4-diacetoxylation in the presence of cobalt tetra(hydroquinone)porphyrin as an electron transfer reagent.
Avvertenze
Danger
Indicazioni di pericolo
Consigli di prudenza
Classi di pericolo
Flam. Liq. 2 - STOT SE 3
Organi bersaglio
Respiratory system
Codice della classe di stoccaggio
3 - Flammable liquids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
66.0 °F
Punto d’infiammabilità (°C)
18.9 °C
Dispositivi di protezione individuale
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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I clienti hanno visto anche
Sarah J Ryan et al.
Journal of the American Chemical Society, 133(13), 4694-4697 (2011-03-12)
Herein we report the first all-carbon N-heterocyclic carbene-catalyzed (4 + 2) cycloaddition. The reaction proceeds with α,β-unsaturated acid fluorides and silyl dienol ethers and produces 1,3-cyclohexadienes with complete diastereocontrol (dr >20:1) while demonstrating a new type of reaction cascade exploiting
Contact formation dynamics: Mapping chemical bond formation between a molecule and a metallic probe.
Borislav Naydenov et al.
Nano letters, 6(8), 1752-1756 (2006-08-10)
We present a study that maps out chemical bond formation between a Pt-inked probe and a single 1,3-cyclohexadiene (1,3-CHD) molecule on Si(100). By separating the mechanical and electronic contributions to the current during the approach to contact, we show that
Enantioselective Platinum?Catalyzed Silicon?Boron Addition to 1, 3?Cyclohexadiene.
Gerdin M and Moberg C
Advanced Synthesis & Catalysis, 347(6), 749-753 (2005)
Marija Kotur et al.
The Journal of chemical physics, 130(13), 134311-134311 (2009-04-10)
We demonstrate the use of shaped ultrafast laser pulses in the deep ultraviolet to control the ring opening isomerization of 1,3-cyclohexadiene to form 1,3,5-hexatriene. The experiments are performed with a gas phase sample and the isomerization yield is probed with
Chemo-, regio-, and stereoselective cobalt-mediated [2+2+2] cycloaddition of alkynyl boronates to alkenes: 1,3- and 1,4-diboryl-1,3-cyclohexadienes.
Vincent Gandon et al.
Angewandte Chemie (International ed. in English), 44(43), 7114-7118 (2005-10-12)
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