Passa al contenuto
Merck
Tutte le immagini(3)

Key Documents

View All Documentation

302546

Sigma-Aldrich

Methyl 2-(bromomethyl)acrylate

97%

Autenticatiper visualizzare i prezzi riservati alla tua organizzazione & contrattuali
Tutte le immagini(3)

About This Item

Formula condensata:
H2C=C(CH2Br)CO2CH3
Numero CAS:
4224-69-5
Peso molecolare:
179.01
Beilstein:
1852481
Numero MDL:
MFCD00011697
Codice UNSPSC:
12162002
ID PubChem:
24858262
NACRES:
NA.23

Saggio

97%

Indice di rifrazione

n20/D 1.490 (lit.)

P. eboll.

35-37 °C/1.3 mmHg (lit.)

Densità

1.489 g/mL at 25 °C (lit.)

Temperatura di conservazione

−20°C

Stringa SMILE

COC(=O)C(=C)CBr

InChI

1S/C5H7BrO2/c1-4(3-6)5(7)8-2/h1,3H2,2H3
CFTUQSLVERGMHL-UHFFFAOYSA-N

Cerchi prodotti simili? Visita Guida al confronto tra prodotti

Applicazioni

Methyl (2-bromomethyl)acrylate (MBrMA) may be used as chain transfer agents in the emulsion polymerization of methyl methacrylate (MMA) and styrene. MBrMA can undergo nucleophilic substitution of carboxylic acid to form methyl 2-(acyloxymethyl)acrylates.

Pittogrammi

CorrosionExclamation mark
GHS05,GHS07

Avvertenze

Danger

Indicazioni di pericolo

H315,H318,H335

Classi di pericolo

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

10 - Combustible liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

172.4 °F - closed cup

Punto d’infiammabilità (°C)

78 °C - closed cup

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Scegli una delle versioni più recenti:

Certificati d'analisi (COA)

Lot/Batch Number
01419LH
05722CH
18321LE
10212HX
07202BE

Non trovi la versione di tuo interesse?

Se hai bisogno di una versione specifica, puoi cercare il certificato tramite il numero di lotto.

Cerca un COA

Possiedi già questo prodotto?

I documenti relativi ai prodotti acquistati recentemente sono disponibili nell’Archivio dei documenti.

Visita l’Archivio dei documenti

I clienti hanno visto anche

Slide 1 of 6

1 of 6

Methyl 3-hydroxy-2-methylenebutyrate 98%

Sigma-Aldrich

404667

Methyl 3-hydroxy-2-methylenebutyrate

Methyl trans-4-bromo-2-butenoate technical, ≥90% (GC)

Sigma-Aldrich

16505

Methyl trans-4-bromo-2-butenoate

α-Methylene-γ-butyrolactone 97%

Sigma-Aldrich

226416

α-Methylene-γ-butyrolactone

Sodium methanesulfinate technical grade, 85%

Sigma-Aldrich

433063

Sodium methanesulfinate

2-Bromoethanol 95%

Sigma-Aldrich

B65586

2-Bromoethanol

Triethylsilane 99%

Sigma-Aldrich

230197

Triethylsilane

Bunichiro Yamada, Shuzo Aoki, Radical polymerization and copolymerization of methyl 2-(acyloxymethyl)acrylate as hindered 2-substituted acrylate
Kobatake S, et al.
Polymer, 36(2), 413-419 (1995)
Mukund P Sibi et al.
Tetrahedron, asymmetry, 17(4), 516-519 (2006-06-27)
We have investigated the effect of nitrogen protecting groups in radical addition trapping experiments leading to beta(2)-amino acids. Of the three N-protecting groups examined, the phthalimido group was optimal with respect to both yields and enantioselectivity. Additionally, radical additions to
Use of methyl 2-(bromomethyl) acrylate as a chain-transfer agent to yield functionalized macromonomers via conventional and living radical polymerizations.
Bon, SAF, et al.
Macromolecules, 33(16), 5819-5824 (2000)
Thomas Mendgen et al.
Bioorganic & medicinal chemistry letters, 20(19), 5757-5762 (2010-08-24)
The enzyme MurA performs an essential step in peptidoglycan biosynthesis and is therefore a target for the discovery of novel antibacterial compounds. We report here the inhibition of MurA by natural products from tulips (tulipalines and tuliposides), and the structure-activity
Fabrice Denes et al.
The Journal of organic chemistry, 72(2), 398-406 (2007-01-16)
Enantioenriched 3,4-disubstituted beta-prolines have been prepared with a high diastereocontrol through a carbometalation reaction or through a domino Michael addition/carbometalation reaction.

Il team dei nostri ricercatori vanta grande esperienza in tutte le aree della ricerca quali Life Science, scienza dei materiali, sintesi chimica, cromatografia, discipline analitiche, ecc..

Contatta l'Assistenza Tecnica.