T67806

Triisopropyl phosphite

95%

• Sinônimo(s): Isopropyl phosphite, Tri-2-propyl phosphite, Triisopropoxyphosphine, Tris(isopropyl) phosphite
• Fórmula linear: [(CH₃)₂CHO]₃P
• Número CAS: 116-17-6
• Peso molecular: 208.24
• Beilstein: 1701528
• Número CE: 204-130-0
• Número MDL: MFCD00008874
• Código UNSPSC: 12352100
• ID de substância PubChem: 24900404
• NACRES: NA.22

Propriedades

• pressão de vapor: <2 mmHg ( 20 °C)
• Nível de qualidade: 200
• Ensaio: 95%
• índice de refração: n20/D 1.411 (lit.)
• pb: 63-64 °C/11 mmHg (lit.)
• densidade: 0.844 g/mL at 25 °C (lit.)
• cadeia de caracteres SMILES: CC(C)OP(OC(C)C)OC(C)C
• InChI: 1S/C9H21O3P/c1-7(2)10-13(11-8(3)4)12-9(5)6/h7-9H,1-6H3
• chave InChI: SJHCUXCOGGKFAI-UHFFFAOYSA-N

Descrição

Aplicação

Triisopropyl phosphite can be used as a reactant:

• With Ru-based indenylidene complexes to form 1^st generation complexes for metathesis reactions.
• In Perkow-type reaction to synthesize compounds containing polarized carbon-carbon double bonds.
• For the synthesis of phosphonohydrazines by reacting with arylamines and isoamyl nitrite.

It can also be used as an alternative to triphenylphosphine in Mitsunobu reaction to facilitate the isolation of products.

Informações de segurança

• Pictogramas: GHS06
• Palavra indicadora: Danger
• Frases de perigo: H301,H315
• Declarações de precaução: P301 + P310 + P330 - P302 + P352
• Classificações de perigo: Acute Tox. 3 Oral - Skin Irrit. 2
• Código de classe de armazenamento: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): 154.4 °F - closed cup
• Ponto de fulgor (°C): 68 °C - closed cup
• Equipamento de proteção individual: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter