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M56557

Sigma-Aldrich

4-Methylmorpholine

ReagentPlus®, 99%

Sinônimo(s):

N-Methylmorpholine, NMM

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About This Item

Fórmula empírica (Notação de Hill):
C5H11NO
Número CAS:
109-02-4
Peso molecular:
101.15
Beilstein:
102719
Número CE:
203-640-0
Número MDL:
MFCD00006175
Código UNSPSC:
12352100
ID de substância PubChem:
57654399
NACRES:
NA.22

grau

reagent

Nível de qualidade

200

densidade de vapor

>1 (vs air)

pressão de vapor

18 mmHg ( 20 °C)

linha de produto

ReagentPlus®

Ensaio

99%

Formulário

liquid

dilution

(for general lab use)

índice de refração

n20/D 1.435 (lit.)

p.e.

115-116 °C/750 mmHg (lit.)

pf

−66 °C (lit.)

densidade

0.92 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

CN1CCOCC1

InChI

1S/C5H11NO/c1-6-2-4-7-5-3-6/h2-5H2,1H3

chave InChI

SJRJJKPEHAURKC-UHFFFAOYSA-N

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Descrição geral

4-methylmorpholine, also known as N-Methylmorpholine, is a cyclic tertiary amine and is commonly used as a highly valuable solvent and a fine chemical for cellulose.

Aplicação

4-Methylmorpholine can be used to synthesize N-butyl-N-methylmorpholinium bromide by reacting with bromobutane.
4-methylmorpholine is used:
  • in the synthesis of N-methylmorpholine-N-oxide (NMMO)
  • as an effective and inexpensive additive for highly enantioselective arylation of aryl aldehydes catalyzed by the (S)-H8-BINOL-Ti(Oi-Pr)2 complex

Informações legais

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Palavra indicadora

Danger

Frases de perigo

H225,H302,H314

Classificações de perigo

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

53.6 °F - closed cup - DIN 51755 Part 1

Ponto de fulgor (°C)

12 °C - closed cup - DIN 51755 Part 1

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificados de análise (COA)

Lot/Batch Number
MKCR0297
MKCQ0949
MKCQ0861
MKCN8436
MKCM7539

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Size-controlled electrochemical synthesis of palladium nanoparticles using morpholinium ionic liquid.
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Korean Journal of Chemical Engineering, 24(6), 1089-1094 (2007)
Christopher N Cultrara et al.
Molecular therapy. Nucleic acids, 18, 863-870 (2019-11-19)
Oligoarginine sequences conjugated to a short cancer-targeting peptide (CTP) selective for the prostate-specific membrane antigen (PSMA) receptor was developed for selective small interfering RNA (siRNA) delivery to a human metastatic/castration-resistant prostate cancer (PCa) cell line, which expresses PSMA on the
Benedetta Del Secco et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 18(9), 2142-2149 (2019-04-24)
Silica nanoparticles (NPs) are versatile nanomaterials, which are safe with respect to biomedical applications, and therefore are highly investigated. The advantages of NPs include their ease of preparation, inexpensive starting materials and the possibility of functionalization or loading with various
L Belin et al.
British journal of industrial medicine, 40(3), 251-257 (1983-08-01)
Investigations of respiratory symptoms among workers in a factory producing polyurethane foam included measurement of air pollution with amines and isocyanates and a simultaneous health investigation of the exposed workers. An increased bronchial reactivity to inhaled methacholine was found in
V Balachandran et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 97, 1101-1110 (2012-08-30)
The experimental FT-IR (4000-400 cm(-1)) and FT-Raman (3500-100 cm(-1)) spectra of 4-Methylmorpholine were recorded. The observed bands were interpreted with the aid of normal coordinate analysis and force field calculations based on density functional theory (DFT) using B3LYP functional theory
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Global Trade Item Number

SKUGTIN
M56557-5L
M56557-100ML4061834060185
M56557-500ML4061834060192
M56557-5ML

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