A36603

Allyltriphenylphosphonium bromide

99%

• Sinônimo(s): 2-Propenyltriphenylphosphonium bromide, NSC 110609, NSC 59815
• Fórmula linear: H₂C=CHCH₂P(C₆H₅)₃Br
• Número CAS: 1560-54-9
• Peso molecular: 383.26
• Número CE: 216-332-6
• Número MDL: MFCD00011808
• Código UNSPSC: 12352002
• ID de substância PubChem: 24890798
• NACRES: NA.22

Propriedades

• Ensaio: 99%
• Formulário: powder
• adequação da reação: reaction type: C-C Bond Formation
• pf: 222-225 °C (lit.)
• cadeia de caracteres SMILES: [Br-].C=CC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C21H20P.BrH/c1-2-18-22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h2-17H,1,18H2;1H/q+1;/p-1
• chave InChI: FWYKRJUVEOBFGH-UHFFFAOYSA-M

Descrição

Aplicação

Reactant for:

• Preparation of a diol and carbamate chemistry library for common functional groups
• Regioselective synthesis of alkenes via semihydrogenation and semihydrogenation-oxidation of dienes
• Alkene addition of frustrated Lewis pairs
• Olefination of N-sulfonyl imines for stereoselective synthesis of vinyl arenes
• Wittig olefination of aldehydes for preparation of conjugated dienes
• Tandem Michael addition / ylide olefination reactions for the synthesis of highly functionalized cyclohexadienes

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: dust mask type N95 (US), Eyeshields, Gloves