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A10507

Sigma-Aldrich

Acetone oxime

98%

Sinônimo(s):

β-Isonitrosopropane, 2-Propanone oxime, Acetoxime, Dimethyl ketoxime, N-Isopropylidenehydroxylamine, Propanone oxime

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About This Item

Fórmula linear:
(CH3)2C=NOH
Número CAS:
127-06-0
Peso molecular:
73.09
Beilstein:
1560146
Número CE:
204-820-1
Número MDL:
MFCD00002118
Código UNSPSC:
12352100
ID de substância PubChem:
24890499
NACRES:
NA.02

Ensaio

98%

forma

crystals

pb

135 °C (lit.)

pf

60-63 °C (lit.)

densidade

0.901 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

C\C(C)=N/O

InChI

1S/C3H7NO/c1-3(2)4-5/h5H,1-2H3

chave InChI

PXAJQJMDEXJWFB-UHFFFAOYSA-N

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Palavra indicadora

Danger

Frases de perigo

H228,H312,H317,H318,H351

Classificações de perigo

Acute Tox. 4 Dermal - Carc. 2 - Eye Dam. 1 - Flam. Sol. 2 - Skin Sens. 1B

Código de classe de armazenamento

4.1B - Flammable solid hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type N95 (US)

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Certificados de análise (COA)

Lot/Batch Number
BCCG6807
BCCG3394
BCCF3205
BCCD4458
BCCC4004

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Sigma-Aldrich

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CHES ≥99.0% (titration)

Sigma-Aldrich

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CHES

Propionamide 97%

Sigma-Aldrich

143936

Propionamide

Nickel(II) chloride 98%

Sigma-Aldrich

339350

Nickel(II) chloride

N-Methylacetamide ≥99%

Sigma-Aldrich

M26305

N-Methylacetamide

Hydroxylamine solution 50 wt. % in H2O

Sigma-Aldrich

438227

Hydroxylamine solution

Acetona HPLC Plus, for HPLC, GC, and residue analysis, ≥99.9%

Sigma-Aldrich

650501

Acetona

Stefanie Zorbas-Seifried et al.
Molecular pharmacology, 71(1), 357-365 (2006-10-20)
The presence of cis-configured exchangeable ligands has long been considered a prerequisite for antitumor activity of platinum complexes, but over the past few years, several examples violating this structure-activity relationship have been recognized. We report here on studies with the
C Kohl et al.
Carcinogenesis, 13(7), 1091-1094 (1992-07-01)
The hepatocarcinogenicity of acetoxime has been tentatively linked with its metabolic oxidation to the potent genotoxicant and carcinogen propane 2-nitronate (P2-N). In order to test the hypothesis that acetoxime is metabolized to P2-N, the oxime (20 mM) was incubated with
R S Sodum et al.
Chemical research in toxicology, 10(12), 1420-1426 (1998-01-23)
Previously, the secondary nitroalkane 2-nitropropane, a strong hepatocarcinogen in rats, had been shown to induce the formation of 8-aminoguanine in both DNA and RNA of rat liver through a sulfotransferase-mediated pathway. This pathway was postulated to convert the carcinogen into
S S Mirvish et al.
Journal of the National Cancer Institute, 69(4), 961-962 (1982-10-01)
Acetoxime was tested for carcinogenicity by chronic administration in the drinking water to male and female outbred MRC-Wistar rats. The dose of 1.0 g/liter was administered 5 days/week for 18 months (total dose, 6.2--7.0 g/rat). The test compound induced benign
P Kreis et al.
Carcinogenesis, 21(2), 295-299 (2000-02-05)
The industrial solvent 2-nitropropane (2-NP) is a genotoxic hepatocarcinogen in rats. The genotoxicity of the compound in rats has been attributed to sulfotransferase-mediated formation of DNA-reactive nitrenium ions from the anionic form of 2-NP, propane 2-nitronate (P2N). Whether human sulfotransferases
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