923451

(PhMPhos)PdCl₂

complex with CH₂Cl₂

• Sinônimo(s): 1-Diadamantylphosphino-1′-diphenylphosphinoferrocene palladium dichloride
• Fórmula empírica (Notação de Hill): C₄₂H₄₈Cl₂FeP₂Pd
• Número CAS: 2768152-18-5
• Peso molecular: 847.95
• Código UNSPSC: 12352101
• NACRES: NA.21

Propriedades

• Nível de qualidade: 100
• Formulário: powder
• adequação da reação: reagent type: catalyst; reaction type: Cross Couplings
• cadeia de caracteres SMILES: ClCCl.[Cl-][Pd+2]1([Cl-])[P](C=2C=CC=CC2)(C=3C=CC=CC3)[C-]45[CH]6=[CH]7[CH]8=[CH]4[Fe+2]789%10%11%1265[CH]=%13[CH]%12=[CH]%11[C-]%10([CH]%139)[P]1(C%14%15CC%16CC(CC(C%16)C%14)C%15)C%17%18CC%19CC(CC(C%19)C%17)C%18
• InChI: InChI=1S/C25H34P.C17H14P.CH2Cl2.2ClH.Fe.Pd/c1-2-4-23(3-1)26(24-11-17-5-18(12-24)7-19(6-17)13-24)25-14-20-8-21(15-25)10-22(9-20)16-25;1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;2-1-3;;;;/h1-4,17-22H,5-16H2;1-14H;1H2;2*1H;;/q2*-1;;;;2*+2/p-2
• chave InChI: CPZZSCIFYJFGRL-UHFFFAOYSA-L

Descrição

Aplicação

(PhMPhos)PdCl₂ is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (PhMPhos)PdCl₂ can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

Outras notas

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

Informações de segurança

• Pictogramas: GHS08,GHS07
• Palavra indicadora: Warning
• Frases de perigo: H315,H319,H351
• Declarações de precaução: P202 - P264 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• Classificações de perigo: Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2
• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable