923524

(tBuMPhos)PdCl₂

• Sinônimo(s): 1-Diadamantylphosphino-1′-di-tert-butylphosphinoferrocene palladium dichloride
• Fórmula empírica (Notação de Hill): C₃₈H₅₆Cl₂FeP₂Pd
• Peso molecular: 807.97
• Código UNSPSC: 12352200
• NACRES: NA.21

Propriedades

• Formulário: powder
• Nível de qualidade: 100
• características do produto alternativo mais ecológico: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• categoria alternativa mais ecológica: Aligned
• cadeia de caracteres SMILES: [Cl-][Pd+2]1([Cl-])[P](C(C)(C)C)(C(C)(C)C)[C-]23[CH]4=[CH]5[CH]6=[CH]2[Fe+2]56789%1043[CH]=%11[CH]%10=[CH]9[C-]8([CH]%117)[P]1(C%12%13CC%14CC(CC(C%14)C%12)C%13)C%15%16CC%17CC(CC(C%17)C%15)C%16
• InChI: InChI=1S/C25H34P.C13H22P.2ClH.Fe.Pd/c1-2-4-23(3-1)26(24-11-17-5-18(12-24)7-19(6-17)13-24)25-14-20-8-21(15-25)10-22(9-20)16-25;1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;;;;/h1-4,17-22H,5-16H2;7-10H,1-6H3;2*1H;;/q2*-1;;;2*+2/p-2
• chave InChI: BJILVUSTVVKBGK-UHFFFAOYSA-L

Descrição

Descrição geral

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Aplicação

(tBuMPhos)PdCl₂ is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing CyMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Outras notas

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable