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905100

Sigma-Aldrich

Ir(p-tBu-ppy)3

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About This Item

Fórmula empírica (Notação de Hill):
C45H48IrN3
Número CAS:
1396451-04-9
Peso molecular:
823.10
Número MDL:
MFCD31924979
Código UNSPSC:
12352101
NACRES:
NA.22

Formulário

powder

adequação da reação

reaction type: Photocatalysis
reagent type: catalyst

cadeia de caracteres SMILES

[Ir](c5c(ccc(c5)C(C)(C)C)c6ncccc6)(c3c(ccc(c3)C(C)(C)C)c4ncccc4)c1c(ccc(c1)C(C)(C)C)c2ncccc2

InChI

1S/3C15H16N.Ir/c3*1-15(2,3)13-9-7-12(8-10-13)14-6-4-5-11-16-14;/h3*4-7,9-11H,1-3H3;

chave InChI

HVSYDKXCADBJCU-UHFFFAOYSA-N

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Tris[2-phenylpyridinato-C2,N]iridium(III), 97%

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Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

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Xiao-Jing Wei et al.
ACS catalysis, 7(10), 7136-7140 (2017-11-08)
The development of synthetic methodologies which provide access to both stereoisomers of α,β-disubstituted olefins is a challenging undertaking. Herein, we describe the development of an operationally simple and stereoselective synthesis of difluoromethylated styrenes via a visible-light photocatalytic decarboxylation strategy using
Amandeep Arora et al.
Organic letters, 18(16), 3996-3999 (2016-08-06)
The 2-azolyl radical, generated from 2-bromoazoles via photocatalysis, is a powerful intermediate for the intermolecular arylation of unmodified (hetero)arenes. The reaction is characterized by mild conditions, operational simplicity, tolerance toward functional and sterically demanding groups, broad scope, and anti-Minisci selectivity.
Eric D Nacsa et al.
Journal of the American Chemical Society, 140(9), 3322-3330 (2018-02-06)
Nature routinely engages alcohols as leaving groups, as DNA biosynthesis relies on the removal of water from ribonucleoside diphosphates by a radical-mediated "spin-center shift" (SCS) mechanism. Alcohols, however, remain underused as alkylating agents in synthetic chemistry due to their low
Facile synthesis and complete characterization of homoleptic and heteroleptic cyclometalated Iridium(III) complexes for photocatalysis
Singh A, et al.
Journal of Organometallic Chemistry, 776, 51-59 (2015)

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