798835

[Ru(phd)₃](PF₆)₂

• Sinônimo(s): Tris(1,10-phenanthroline-5,6-dione)ruthenium(II) bis(hexafluorophosphate)
• Fórmula empírica (Notação de Hill): C₃₆H₁₈F₁₂N₆O₆P₂Ru
• Número CAS: 184023-77-6
• Peso molecular: 1021.56
• Código UNSPSC: 12352202
• ID de substância PubChem: 329768673
• NACRES: NA.22

Propriedades

• forma: powder
• adequação da reação: core: ruthenium; reagent type: catalyst
• cadeia de caracteres SMILES: F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.O=C1C2=C(C3=NC=CC=C3C1=O)N=CC=C2.O=C4C(C=CC=N5)=C5C6=C(C4=O)C=CC=N6.O=C7C8=CC=CN=C8C9=C(C7=O)C=CC=N9.[Ru+2]
• InChI: 1S/3C12H6N2O2.2F6P.Ru/c3*15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10;2*1-7(2,3,4,5)6;/h3*1-6H;;;/q;;;2*-1;+2
• chave InChI: LGAOGZFZNIEFHF-UHFFFAOYSA-N

Descrição

Aplicação

In combination with Co(salophen), (Aldrich 345652), [Ru(phd)₃](PF₆)₂ is utilized in the aerobic oxidation of tetrahydroquinolines at room temperature to form quinolines. Unlike previous catalyst systems, the reported application is highly efficient under the presence of atmospheric oxygen.

Informações legais

Modular o-Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions

Informações de segurança

• Código de classe de armazenamento: 13 - Non Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable