71320

Borohidreto de sódio

purum p.a., ≥96% (gas-volumetric)

• Sinônimo(s): Tetraidrodoborato de sódio
• Fórmula linear: NaBH₄
• Número CAS: 16940-66-2
• Peso molecular: 37.83
• Número CE: 241-004-4
• Número MDL: MFCD00003518
• Código UNSPSC: 26111700
• ID de substância PubChem: 57652284
• NACRES: NA.22

Propriedades

• grau: purum p.a.
• Nível de qualidade: 200
• Ensaio: ≥96% (gas-volumetric)
• forma: powder
• adequação da reação: reagent type: reductant
• pf: >300 °C (dec.) (lit.)
• traços de ânion: chloride (Cl^-): ≤5000 mg/kg; sulfate (SO₄^2-): ≤50 mg/kg
• traços de cátion: Ca: ≤50 mg/kg; Cd: ≤50 mg/kg; Co: ≤50 mg/kg; Cu: ≤50 mg/kg; Fe: ≤50 mg/kg; K: ≤1000 mg/kg; Ni: ≤50 mg/kg; Pb: ≤50 mg/kg; Zn: ≤50 mg/kg
• cadeia de caracteres SMILES: [BH4-].[Na+]
• InChI: 1S/BH4.Na/h1H4;/q-1;+1
• chave InChI: YOQDYZUWIQVZSF-UHFFFAOYSA-N

Descrição

Descrição geral

Sodium borohydride is considered as a selective reducing agent due to its ability to selectively reduce aldehydes and ketones into their corresponding alcohols in the presence of other functional groups such as nitro, ester, amide, lactone, epoxide, and nitriles that are otherwise susceptible to reduction. It is being considered as a promising candidate for hydrogen storage applications.

Aplicação

Sodium borohydride may be used as a reductant and hydrogen source for the semi-hydrogenation of alkynes to the corresponding alkenes in the presence of nickel nanoparticles generated in situ from nickel chloride and methanol. It can also be used as a reducing agent for the synthesis of gold nanoparticles from gold chloride.

Outras notas

Reduction of carboxylic acid derivatives

Informações de segurança

• Pictogramas: GHS02,GHS05,GHS06,GHS08
• Palavra indicadora: Danger
• Frases de perigo: H260 - H301 - H314 - H360FD
• Declarações de precaução: P231 + P232 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Classificações de perigo: Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react 1
• Perigos de suplementos: EUH014
• Código de classe de armazenamento: 4.3 - Hazardous materials, which set free flammable gases upon contact with water
• Classe de risco de água (WGK): WGK 2
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges