700665

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

• Sinônimo(s): (R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate
• Fórmula empírica (Notação de Hill): C₄₈H₂₉O₄P
• Número CAS: 864943-22-6
• Peso molecular: 700.72
• Número MDL: MFCD12546016
• Código UNSPSC: 12352005
• ID de substância PubChem: 329762222
• NACRES: NA.22

Propriedades

• Formulário: solid
• Nível de qualidade: 100
• atividade óptica: [α]22/D −44.0°, c = 1 in DMSO
• pf: 390-400 °C
• grupo funcional: phosphate
• temperatura de armazenamento: −20°C
• cadeia de caracteres SMILES: OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)-c6cc7ccccc7c8ccccc68)-c9cc%10ccccc%10c%11ccccc9%11
• InChI: 1S/C48H29O4P/c49-53(50)51-47-43(41-25-29-13-1-5-17-33(29)37-21-9-11-23-39(37)41)27-31-15-3-7-19-35(31)45(47)46-36-20-8-4-16-32(36)28-44(48(46)52-53)42-26-30-14-2-6-18-34(30)38-22-10-12-24-40(38)42/h1-28H,(H,49,50)
• chave InChI: BVICVEIKBNVROI-UHFFFAOYSA-N

Descrição

Aplicação

Catalyst for:

• Asymmetric hydrogenation cascade
• Enantioselective Friedel-Crafts reaction
• Asymmetric hydrogenation of 2-substituted quinolines
• Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates
• Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters
• Asymmetric transfer hydrogenation of substituted quinoxalines

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Gloves, type N95 (US)