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661384

Sigma-Aldrich

2-Iodoxybenzoic acid

contains stabilizer, 45 wt. % (IBX)

Sinônimo(s):

SIBX, Stabilized IBX

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About This Item

Fórmula empírica (Notação de Hill):
C7H5IO4
Número CAS:
61717-82-6
Peso molecular:
280.02
Número MDL:
MFCD02912492
Código UNSPSC:
12352005
ID de substância PubChem:
24884529
NACRES:
NA.22

forma

solid

Nível de qualidade

100

contém

stabilizer

adequação da reação

reagent type: oxidant

concentração

45 wt. % (IBX)

cadeia de caracteres SMILES

OI1(=O)OC(=O)c2ccccc12

InChI

1S/C7H5IO4/c9-7-5-3-1-2-4-6(5)8(10,11)12-7/h1-4H,(H,10,11)

chave InChI

CQMJEZQEVXQEJB-UHFFFAOYSA-N

Categorias relacionadas

Aplicação

Stabilized 2-Iodoxybenzoic Acid (SIBX)
A stabilized formulation of IBX (SIBX) that displays none of the explosive properties of IBX, while maintaining excellent reactivity and selectivity.
Reagent used to oxidize Fmoc-protected amino alcohols to the corresponding amino aldehydes in the presence of DMSO.

Outras notas

The material is stabilized with benzoic acid and isophthalic acid

Palavra indicadora

Danger

Frases de perigo

H314,H335,H372

Classificações de perigo

Eye Dam. 1 - Skin Corr. 1 - STOT RE 1 Inhalation - STOT SE 3

Órgãos-alvo

Lungs, Respiratory system

Perigos de suplementos

EUH044

Código de classe de armazenamento

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificados de análise (COA)

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Aurélie Ozanne et al.
Organic letters, 5(16), 2903-2906 (2003-08-02)
[reaction: see text] SIBX is a nonexplosive formulation of IBX that can be used as a suspension in a variety of standard organic solvents such as refluxing EtOAc and THF to oxidize safely alcohols into aldehydes and ketones. The use
Roberta Bernini et al.
Journal of agricultural and food chemistry, 65(31), 6506-6512 (2017-03-14)
A hydroxytyrosol (HTyr)-enriched fraction containing HTyr 6% w/w, derived from Olea europaea L. byproducts and obtained using an environmentally and economically sustainable technology, was lipophilized under green chemistry conditions. The effects of three fractions containing hydroxytyrosyl butanoate, octanoate, and oleate
Synthetic Communications, 37, 3493-3493 (2007)
Celine L Hartman et al.
Journal of lipid research, 59(1), 113-122 (2017-11-24)
Endothelial dysfunction is a hallmark of multiple inflammatory diseases. Leukocyte interactions with the endothelium have significant effects on vascular wall biology and pathophysiology. Myeloperoxidase (MPO)-derived oxidant products released from leukocytes are potential mediators of inflammation and endothelial dysfunction. 2-Chlorofatty acids
Jane McHowat et al.
Frontiers in physiology, 11, 460-460 (2020-05-28)
Endothelial activation and dysfunction are hallmarks of inflammation. Neutrophil-vascular endothelium interactions have significant effects on vascular wall physiology and pathology. Myeloperoxidase (MPO)-derived products released from activated neutrophils can mediate the inflammatory response and contribute to endothelial dysfunction. 2-Chlorofatty aldehyde (2-ClFALD)

Artigos

Stabilized 2-Iodoxybenzoic Acid (SIBX)

IBX is not often used due to the fact that it is an impact-sensitive explosive material, which prevents its shipping and transport, as well as its application in industry.

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