65671

(R)-1-{(R_P)-2-[2-(Diphenylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine

≥97%

• Sinônimo(s): (1S)-1-[(1R)-1-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ethyl]-2-[2-(diphenylphosphino)phenyl]ferrocene, Walphos SL-W001-2
• Fórmula empírica (Notação de Hill): C₄₆H₃₂F₁₂FeP₂
• Número CAS: 387868-06-6
• Peso molecular: 930.52
• Número MDL: MFCD08561122
• Código UNSPSC: 12352101
• ID de substância PubChem: 24884219
• NACRES: NA.22

Propriedades

• Nível de qualidade: 100
• Ensaio: ≥97%
• pureza óptica: ee: ≥99%
• grupo funcional: fluoro; phosphine
• cadeia de caracteres SMILES: [Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2c3ccccc3P(c4ccccc4)c5ccccc5)P(c6cc(cc(c6)C(F)(F)F)C(F)(F)F)c7cc(cc(c7)C(F)(F)F)C(F)(F)F
• InChI: 1S/C41H27F12P2.C5H5.Fe/c1-25(34-16-10-17-35(34)36-15-8-9-18-37(36)55(30-11-4-2-5-12-30)31-13-6-3-7-14-31)54(32-21-26(38(42,43)44)19-27(22-32)39(45,46)47)33-23-28(40(48,49)50)20-29(24-33)41(51,52)53;1-2-4-5-3-1;/h2-25H,1H3;1-5H;/t25-;;/m0../s1
• chave InChI: LKNKYBWIZNAXBY-WLOLSGMKSA-N

Descrição

Descrição geral

The product is an air-stable and non-hygroscopic Solvias chiral phosphine ligand.

Aplicação

Walphos SL-W001-2, in the presence of a ruthenium catalyst may be used as a ligand in the following processes:

• Asymmetric hydrogenation of IPCA-D, a cinnamic acid derivative.
• Addition of 3,5-difluorophenylketimine to 4-methoxyphenylboronic acid to form the corresponding tertiary substituted cyclic sulfamate derivative with high enantioselctivity.2

Embalagem

Bottomless glass bottle. Contents are inside inserted fused cone.

Outras notas

sold in collaboration with Solvias AG

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Gloves, type N95 (US)