88717

(R)-1-[(S_P)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine

≥97%

• Sinônimo(s): (2R)-1-[(1R)-1-(Dicyclohexylphosphino)ethyl]-2-(diphenylphosphino)ferrocene (acc to CAS), (R)-(S)-Josiphos, Josiphos SL-J001-1
• Fórmula empírica (Notação de Hill): C₃₆H₄₄FeP₂ · C₂H₅OH
• Número CAS: 155806-35-2
• Peso molecular: 640.60
• Número MDL: MFCD00800284
• Código UNSPSC: 12352005
• ID de substância PubChem: 24888985
• NACRES: NA.22

Propriedades

• descrição: ethanol adduct
• Ensaio: ≥97%
• Formulário: powder
• pureza óptica: ee: ≥99%
• grupo funcional: phosphine
• cadeia de caracteres SMILES: [Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)P(C5CCCCC5)C6CCCCC6
• InChI: 1S/C31H39P2.C5H5.Fe/c1-25(32(26-15-6-2-7-16-26)27-17-8-3-9-18-27)30-23-14-24-31(30)33(28-19-10-4-11-20-28)29-21-12-5-13-22-29;1-2-4-5-3-1;/h4-5,10-14,19-27H,2-3,6-9,15-18H2,1H3;1-5H;/t25-;;/m1../s1
• chave InChI: HGTBZFMPHBAUCQ-KHZPMNTOSA-N

Descrição

Descrição geral

(R)-1-[(S_P)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ((R,S)-josiphos) is a chiral ferrocenyl diphosphine ligand.

sold in collaboration with Solvias AG

Aplicação

It may be used in the preparation of cyclopentadienyliridium complexes, [IrCl(PP)]₂ and [IrCp(PP)]. (Cp= cyclopentadienyl; PP= (R)-1-[(S_P)-2-(diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine)

Rhodium complex of (R)-(S)-JOSIPHOS can be used as a catalyst for the selective asymmetric hydrogenation of:       

• Z-β-aryl-β-(enamido)phosphonates.     
•  o-alkoxy tetrasubstituted enamides to yield β-amino alcohol analogs with excellent enantiomeric excess.

Embalagem

Bottomless glass bottle. Contents are inside inserted fused cone.

Informações de segurança

• Código de classe de armazenamento: 11 - Combustible Solids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Gloves, type N95 (US)