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Sigma-Aldrich

Poly(3,4-ethylenedioxythiophene), tetramethacrylate end-capped solution

0.5 wt. % (dispersion in propylene carbonate), contains p-toluenesulfonate as dopant

Sinônimo(s):

Oligotron PC, PEDOT, PEDOT, tetramethacrylate end-capped

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About This Item

Número CE:
Número MDL:
Código UNSPSC:
12352103
NACRES:
NA.23

peso molecular

~1,360-1,600 g/mol (methacrylate equivalent weight)
average Mn ~6,000(lit.)

Nível de qualidade

contém

p-toluenesulfonate as dopant

composição

Oligotron tetramethacrylate, 0.5 wt. %
propylene carbonate, 99.5 wt. %

concentração

0.5 wt. % (dispersion in propylene carbonate)

resistência

1-10 M Ω/sq (typical surface resistance of film)

condutividade

0.1-0.5 S/cm (bulk)

densidade

1.189 g/mL at 25 °C

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Descrição geral

Please follow this link for Aedotron/Oligotron selection guide table.
Poly(3,4-ethylenedioxythiophene), tetramethacrylate end-capped solution (PEDOT-Meth) is a semiconductor based polymer that is functionalized with tetramethacrylate that facilitates effective crosslinking of the conjugated films.
The main characteristic of Oligotron PC is that it behaves as a reactive oligomer in non-volatile solvent. Used blended with monomers, or for reactions with functional compounds.

Aplicação

For best results, agitate for 20 minutes prior to use. Films cast from propylene carbonate will require heat to dry. Photocurable inks can be formulated by adding acrylate monomers and photoinitiators (i.e. DMPA). Propylene carbonate will remain in the polymer. Functional compounds can be coupled to the oligomer via reactions at the methacrylate group.
PEDOT-Meth can be used as a plasticizing membrane in the fabrication of ion-selective sensors and light emitting diodes.
Product can be blended with additional acrylate or methacrylate monomers and crosslinked to make polymer blends. Custom molecules can be synthesized by bonding functional compounds, via the methacrylate groups, to the conducting EDOT oligomers.

Características e benefícios

End-capped structure renders the conducting oligomer PEDOT dispersible. The methacrylate groups offer the potential for crosslinking, or addtional chemical functionalization. Completely dried Oligotron(TM) tetramethacrylate via the methacrylate functional groups.

Atenção

Store this product at room temperature (do not refrigerate or freeze). Some settling will normally occur. Agitate, sonicate, and filter prior to use. A plug of glass wool in a pipette can be used for easy filtration. The shelf life of this product will vary depending on how it is stored and handled. Product should be discarded if heavy aggregation occurs, or if sonication / filtering are inadequate to produce a good casting solution.

Informações legais

Oligotron is a trademark of TDA Research, Inc.

Pictogramas

Exclamation mark

Palavra indicadora

Warning

Frases de perigo

Declarações de precaução

Classificações de perigo

Eye Irrit. 2

Código de classe de armazenamento

10 - Combustible liquids

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

269.6 °F - closed cup

Ponto de fulgor (°C)

132 °C - closed cup


Certificados de análise (COA)

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Composite Polyacrylate- Poly (3, 4-ethylenedioxythiophene) Membranes for Improved All-Solid-State Ion-Selective Sensors
Rzewuska A, et al.
Analytical Chemistry, 80(1), 321-327 (2008)
Synthesis of water-free PEDOT with polyvinylpyrrolidone stabilizer in organic dispersant system
He J, et al.
Organic Electronics, 53, 117-126 (2018)
Cristina Ocaña et al.
Talanta, 186, 279-285 (2018-05-23)
We report here the fabrication of solid-contact calcium-selective electrodes (Ca2+-SCISEs) made of a polyurethane acrylate ion-selective membrane (ISM) that was covalently attached to the underlying ion-to-electron transducer (solid-contact). Methacrylate-functionalized poly(3,4-ethylenedioxythiophene) (Meth-PEDOT) and Meth-PEDOT films containing either multiwalled carbon nanotubes (MWCNT)

Artigos

Progress in Organic Thermoelectric Materials & Devices including high ZT values of >0.2 at room temperature by p-type (PEDOT:PSS) & n-type (Poly[Kx(Ni-ett)]) materials are discussed.

The application of conducting polymers at the interface with biology is an exciting new trend in organic electronics research.

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