443328
N-Isopropyl-N-methyl-tert-butylamine
98%
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About This Item
Fórmula linear:
(CH3)3CN(CH3)CH(CH3)2
Número CAS:
Peso molecular:
129.24
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22
Produtos recomendados
Nível de qualidade
Ensaio
98%
forma
liquid
índice de refração
n20/D 1.419 (lit.)
pb
127 °C (lit.)
densidade
0.767 g/mL at 25 °C (lit.)
grupo funcional
amine
cadeia de caracteres SMILES
CC(C)N(C)C(C)(C)C
InChI
1S/C8H19N/c1-7(2)9(6)8(3,4)5/h7H,1-6H3
chave InChI
WYLLBTPEHIVUKV-UHFFFAOYSA-N
Descrição geral
N-Isopropyl-N-methyl-tert-butylamine is a tertiary amine. BH3.THF stabilized by N-isopropyl N-methyl tert-butylamine is useful for the carbonyl reductions.
Aplicação
N-Isopropyl-N-methyl-tert-butylamine may be used to stabilize the borane-THF solutions. It may also be used for the synthesis of rotaxane, via Sonogashira coupling.
Palavra indicadora
Danger
Frases de perigo
Declarações de precaução
Classificações de perigo
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
Órgãos-alvo
Respiratory system
Código de classe de armazenamento
3 - Flammable liquids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
48.2 °F - closed cup
Ponto de fulgor (°C)
9 °C - closed cup
Equipamento de proteção individual
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Dominic Thibeault et al.
Molecules (Basel, Switzerland), 15(5), 3709-3730 (2010-07-27)
The number of synthetic methods enabling the preparation of ammonium-based rotaxanes has increased very rapidly in the past ten years. The challenge in the synthesis of rotaxanes results from the rather weak interactions between the ammonium-containing rod and the crown
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Organic letters, 9(9), 1793-1795 (2007-04-03)
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Organic Process Research & Development, 11(2), 210-214 (2007)
Jeffrey A Crank et al.
Journal of the American Society for Mass Spectrometry, 20(10), 1790-1800 (2009-08-12)
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