270997

Diclorometano

anhydrous, ≥99.8%, contains 40-150 ppm amylene as stabilizer

• Sinônimo(s): Cloreto de metileno
• Fórmula empírica (Notação de Hill): CH₂Cl₂
• Número CAS: 75-09-2
• Peso molecular: 84.93
• Beilstein: 1730800
• Número CE: 200-838-9
• Número MDL: MFCD00000881
• Código UNSPSC: 12352101
• ID de substância PubChem: 57648216
• NACRES: NA.21

Propriedades

• grau: anhydrous
• Nível de qualidade: 200
• Agency: suitable for EPA 1613
• densidade de vapor: 2.9 (vs air)
• pressão de vapor: 24.45 psi ( 55 °C); 6.83 psi ( 20 °C); 6.86 psi ( 20 °C)
• Ensaio: ≥99.8%
• Formulário: liquid
• temperatura de autoignição: 1223 °F
• contém: 40-150 ppm amylene as stabilizer
• Lim. expl.: 22 %
• técnica(s): gas chromatography (GC): suitable
• Impurezas: ≤0.001% water; ≤0.005% water (100 mL pkg)
• resíduo de evaporação: <0.0005%
• índice de refração: n20/D 1.424 (lit.)
• p.e.: 39.8-40 °C (lit.)
• pf: −95 °C (lit.)
• densidade: 1.325 g/mL at 25 °C (lit.)
• cadeia de caracteres SMILES: ClCCl
• InChI: 1S/CH2Cl2/c2-1-3/h1H2
• chave InChI: YMWUJEATGCHHMB-UHFFFAOYSA-N

Descrição

Descrição geral

Dichloromethane has been tested as a solvent medium for the dipyridine-chromium(VI) oxide. Solubility was reported to be 12.5g/100ml. Role of quantity of TiO₂ loading on activated carbon support employed in the photodecomposition of dichloromethane has been investigated.

Dichloromethane is a chlorinated organic solvent that is susceptible to degradation with time. This can be suppressed by adding amylene as a stabilizer.

Aplicação

Dichloromethane has been used for the quantification of herbivore (gypsy moth) induced blueberry volatiles by gas chromatography (GC).

Dichloromethane may be used as a solvent for the oxidation of primary and secondary alcohols using dipyridine-chromium(VI) oxide. Lithium perchlorate suspended in DCM is an effective medium for Mukaiyama aldol reactions of aldehydes with silyl ketene acetal. DCM may also be used as solvent for the synthesis of 2-bromo-6-lithiopyridine from 2,6-dibromopyridine via lithium-bromine exchange reaction.

Embalagem

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Outras notas

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Informações de segurança

• Pictogramas: GHS08,GHS07
• Palavra indicadora: Warning
• Frases de perigo: H315,H319,H336,H351
• Declarações de precaução: P202 - P261 - P264 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• Classificações de perigo: Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Órgãos-alvo: Central nervous system
• Código de classe de armazenamento: 6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
• Classe de risco de água (WGK): WGK 2
• Ponto de fulgor (°F): does not flash
• Ponto de fulgor (°C): does not flash
• Equipamento de proteção individual: Eyeshields, Faceshields, Gloves