341347

Bis(diisopropylamino)chlorophosphine

≥95.0%

• Sinônimo(s): Chlorobis(N,N-diisopropyl)phosphoramidite, Chlorobis(N,N-diisopropylamino)phosphine, Tetraisopropylphosphorodiamidous chloride
• Fórmula linear: [[(CH₃)₂CH]₂N]₂PCl
• Número CAS: 56183-63-2
• Peso molecular: 266.79
• Número MDL: MFCD00061482
• Código UNSPSC: 12352001
• ID de substância PubChem: 24860930
• NACRES: NA.22

Propriedades

• Ensaio: ≥95.0%
• adequação da reação: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling
• pf: 100-104 °C (lit.)
• grupo funcional: phosphine
• cadeia de caracteres SMILES: CC(C)N(C(C)C)P(Cl)N(C(C)C)C(C)C
• InChI: 1S/C12H28ClN2P/c1-9(2)14(10(3)4)16(13)15(11(5)6)12(7)8/h9-12H,1-8H3
• chave InChI: FEHUTHGOLLQBNW-UHFFFAOYSA-N

Descrição

Aplicação

Bis(diisopropylamino)chlorophosphine has been used in the synthesis of tert-butyl tetraisopropylphosphorodiamidite ligand for palladium-catalyzed Buchwald–Hartwig amination reaction.

It is also can be used to synthesize:

• acyclic N-phosphonio imine catalyst for selective epoxidations
• boryl-substituted methylenephosphonium derivatives

Outras notas

Contains varying amounts of diisopropylamine hydrochloride

Informações de segurança

• Pictogramas: GHS05
• Palavra indicadora: Danger
• Frases de perigo: H314
• Declarações de precaução: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Classificações de perigo: Eye Dam. 1 - Skin Corr. 1B
• Código de classe de armazenamento: 8A - Combustible corrosive hazardous materials
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): Not applicable
• Ponto de fulgor (°C): Not applicable
• Equipamento de proteção individual: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges