302759

Benzylmagnesium chloride solution

1.0 M in diethyl ether

• Sinônimo(s): (Phenylmethyl)magnesium chloride, Benzylchloromagnesium, Chloro(phenylmethyl)magnesium
• Fórmula linear: C₆H₅CH₂MgCl
• Número CAS: 6921-34-2
• Peso molecular: 150.89
• Beilstein: 878506
• Número MDL: MFCD00000469
• Código UNSPSC: 12352103
• ID de substância PubChem: 24858271
• NACRES: NA.22

Propriedades

• Nível de qualidade: 100
• adequação da reação: reaction type: Grignard Reaction
• concentração: 1.0 M in diethyl ether
• densidade: 0.794 g/mL at 25 °C
• grupo funcional: phenyl
• cadeia de caracteres SMILES: Cl[Mg]Cc1ccccc1
• InChI: 1S/C7H7.ClH.Mg/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1
• chave InChI: NRAFPLGJPPJUNB-UHFFFAOYSA-M

Descrição

Descrição geral

Benzylmagnesium chloride is a versatile Grignard reagent frequently used in organic synthesis. It can be used as a reagent in the addition reaction with carbonyl compounds, nitriles, epoxides, and alkyl halides to synthesize various alcohols, amines, and ketones. Additionally, it is also used in reductions, cross-coupling, allylation and alkylation reactions.

Aplicação

Benzylmagnesium chloride solution (1.0 M in diethyl ether) is used as a reagent to provide the benzyl group required for the synthesis of the desired sulfonic acid-functionalized alkoxysilane. It is also used in the anionic polymerization of styrene to form styrenyl magnesium chloride, which is further used as an initiator in the synthesis of polyolefin-block-polystyrene block copolymers.

Informações de segurança

• Pictogramas: GHS02,GHS05,GHS07
• Palavra indicadora: Danger
• Frases de perigo: H225,H302,H314,H336
• Declarações de precaução: P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Classificações de perigo: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• Órgãos-alvo: Central nervous system
• Perigos de suplementos: EUH019
• Código de classe de armazenamento: 3 - Flammable liquids
• Classe de risco de água (WGK): WGK 2
• Ponto de fulgor (°F): -40.0 °F - closed cup
• Ponto de fulgor (°C): -40 °C - closed cup
• Equipamento de proteção individual: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter