159239
2-Bromoanisole
97%
Sinônimo(s):
1-Bromo-2-methoxybenzene
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About This Item
Fórmula linear:
BrC6H4OCH3
Número CAS:
Peso molecular:
187.03
Beilstein:
1859996
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22
Produtos recomendados
Ensaio
97%
Formulário
liquid
índice de refração
n20/D 1.573 (lit.)
p.e.
223 °C (lit.)
pf
2 °C (lit.)
densidade
1.502 g/mL at 25 °C (lit.)
grupo funcional
bromo
cadeia de caracteres SMILES
COc1ccccc1Br
InChI
1S/C7H7BrO/c1-9-7-5-3-2-4-6(7)8/h2-5H,1H3
chave InChI
HTDQSWDEWGSAMN-UHFFFAOYSA-N
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Descrição geral
Diffusion coefficients of 2-bromoanisole at infinite dilution in supercritical carbon dioxide has been evaluated by Taylor-Aris chromatographic technique.
Aplicação
2-Bromoanisole was used in the synthesis of unsymmetrically substituted biphenyl compounds. It was also used in the preparation of the family of exo-[n.m.n.m]metacyclophanes (n,m > or = 3).
Palavra indicadora
Warning
Frases de perigo
Declarações de precaução
Classificações de perigo
Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2
Código de classe de armazenamento
10 - Combustible liquids
Classe de risco de água (WGK)
WGK 1
Ponto de fulgor (°F)
208.4 °F - closed cup
Ponto de fulgor (°C)
98 °C - closed cup
Equipamento de proteção individual
Eyeshields, Gloves
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Patrick T Weiser et al.
Bioorganic & medicinal chemistry, 22(2), 917-926 (2013-12-24)
A series of unsymmetrically substituted biphenyl compounds was designed as alpha helical proteomimetics with the aim of inhibiting the binding of coactivator proteins to the nuclear hormone receptor coactivator binding domain. These compounds were synthesized in good overall yields in
Burns et al.
The Journal of organic chemistry, 65(17), 5185-5196 (2000-09-19)
A general strategy for the preparation of the family of exo-[n.m.n.m]metacyclophanes (n,m > or = 3) in 6-steps (starting from 2-bromoanisole) that utilizes a [2 + 2] approach to furnish the exo-metacyclophane ring in good to moderate yield is described.
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Herein we present half-sandwich IrIII complexes [(η5-Cpxbiph)Ir(OˆC)Cl] containing OˆC(NHC)-chelating ligand as anticancer and antimetastasis agents. All the complexes displayed high potency in vitro against a wide range of cancer cells. In addition, Ir2 significantly curb tumor growth in a colon
Diffusion coefficients of 2-fluoroanisole, 2-bromoanisole, allylbenzene and 1, 3-divinylbenzene at infinite dilution in supercritical carbon dioxide
Suarez-Iglesias O, et al.
Fluid Phase Equilibria, 260(2), 279-286 (2007)
Nicholas C Pflug et al.
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