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Merck
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Key Documents

127566

Sigma-Aldrich

Bis(diphenylphosphino)methane

97%

Sinônimo(s):

DPPM, Methanediylbis[diphenylphosphine, Tetraphenylmethylenediphosphine, DPM, Methylenebis(diphenylphosphine)

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About This Item

Fórmula linear:
(C6H5)2PCH2P(C6H5)2
Número CAS:
Peso molecular:
384.39
Beilstein:
758760
Número CE:
Número MDL:
Código UNSPSC:
12352002
ID de substância PubChem:
NACRES:
NA.22

Ensaio

97%

forma

solid

adequação da reação

reagent type: ligand
reaction type: Heck Reaction

reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

pf

118-119 °C (lit.)

grupo funcional

phosphine

cadeia de caracteres SMILES

C(P(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4

InChI

1S/C25H22P2/c1-5-13-22(14-6-1)26(23-15-7-2-8-16-23)21-27(24-17-9-3-10-18-24)25-19-11-4-12-20-25/h1-20H,21H2

chave InChI

XGCDBGRZEKYHNV-UHFFFAOYSA-N

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Categorias relacionadas

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type N95 (US)


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Robert R A Freund et al.
Dalton transactions (Cambridge, England : 2003), 43(37), 13988-14000 (2014-08-15)
A series of allyl modified nickelalactone derivatives of the general formula [(L)nNi{CH2C(CH3)C(CH3)CH2COO}] was synthesized via ligand exchange reactions in order to investigate the influence of the neutral ligand L on the structure and stability of these complexes. While the square
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