Skip to Content
MilliporeSigma
All Photos(1)

Key Documents

902896

Sigma-Aldrich

Black phosphorus

>=20 micro gram/ml in NMP

Synonym(s):

2D Black phosphorus, Phosphorene

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
P
UNSPSC Code:
12161600
NACRES:
NA.23

form

liquid

General description

Black phosphorus, also known as phosphorene, is a stable allotrope of phosphorus with semiconducting properties. It has a good mechanical property and a tunable band structure. BP also has good anisotropic thermal, electrical and optical properties.

Application

BP is a two dimensional (2D) p-type material, which shows high hole mobility up to 1000 cm2V-1s-1. It can be used in the fabrication of energy storage devices such as lithium-ion batteries. BP can also be used in a variety of biomedical applications such as photodynamic therapy.
Owing to the unique properties such as thickness dependent tunable band gap, strong in-plane anisotropy, and high carrier mobility, 2D-black phosphorous has attracted significant attention recently. The applications of 2D-black phosphorous extend from electronics, to optoelectronics, spintronics, thermoelectrics and storage devices.

Caution

Material is very oxygen sensitive. Please handle under inert atmosphere.

pictograms

Health hazardExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 1

flash_point_f

195.8 °F - closed cup

flash_point_c

91 °C - closed cup


Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Production of few-layer phosphorene by liquid exfoliation of black phosphorus.
Brent, et al.
Chemical Communications (Cambridge, England), 50, 13338-13341 (2014)
Applications of Phosphorene and Black Phosphorus in Energy Conversion and Storage Devices.
Pang J, et al.
Advanced Energy Materials, 8, 1702093-1702093 (2018)
Phosphorene: An Unexplored 2D Semiconductor with a High Hole Mobility.
Liu H, et al.
ACS Nano, 8, 4033-4041 (2014)
Phosphorene: Synthesis, Scale-Up, and Quantitative Optical Spectroscopy.
Woomer, et al.
ACS Nano, 9, 8869-8884 (2015)
Recent advances in synthesis, properties, and applications of phosphorene.
Akhtar M, et al.
NPJ 2D materials and applications, 5, 1-1 (2017)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service