Skip to Content
MilliporeSigma
All Photos(4)

Key Documents

More Documents

774677

Sigma-Aldrich

Cyclohexylmagnesium chloride solution

greener alternative

1.0 M in 2-methyltetrahydrofuran

Synonym(s):

Chlorocyclohexylmagnesium

Sign Into View Organizational & Contract Pricing
All Photos(4)

About This Item

Empirical Formula (Hill Notation):
C6H11ClMg
CAS Number:
931-51-1
Molecular Weight:
142.91
Beilstein/REAXYS Number:
3535440
MDL number:
MFCD00003816
UNSPSC Code:
12352103
PubChem Substance ID:
329767705
NACRES:
NA.22

form

solution

reaction suitability

reaction type: Grignard Reaction

greener alternative product characteristics

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

1.0 M in 2-methyltetrahydrofuran

density

0.915 g/mL at 25 °C

greener alternative category

, Aligned

storage temp.

2-8°C

SMILES string

Cl[Mg]C1CCCCC1

InChI

1S/C6H11.ClH.Mg/c1-2-4-6-5-3-1;;/h1H,2-6H2;1H;/q;;+1/p-1

InChI key

WMJMABVHDMRMJA-UHFFFAOYSA-M

Looking for similar products? Visit Product Comparison Guide

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Click here for more information.

Application

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
Nucleophilic reagent is commonly used in substitution and addition reactions.

Packaging

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Other Notes

Development of GSK′s reagent guides – embedding sustainability into reagent selection.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

supp_hazards

EUH014,EUH019

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

14.0 °F

flash_point_c

-10 °C

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service