687952

(Cyclohexylmethyl)magnesium bromide solution

• Synonym(s): Cyclohexylmethylmagnesium bromide
• Empirical Formula (Hill Notation): C₇H₁₃BrMg
• CAS Number: 35166-78-0
• Molecular Weight: 201.39
• MDL number: MFCD02260210
• UNSPSC Code: 12352103
• PubChem Substance ID: 329760828
• NACRES: NA.22

Properties

• Quality Level: 100
• form: liquid
• reaction suitability: reaction type: Grignard Reaction
• density: 0.966 g/mL at 25 °C
• SMILES string: Br[Mg]CC1CCCCC1
• InChI: 1S/C7H13.BrH.Mg/c1-7-5-3-2-4-6-7;;/h7H,1-6H2;1H;/q;;+1/p-1
• InChI key: ZBCIOGFGZRNNEC-UHFFFAOYSA-M

Description

Application

Reactant involved in:

• Isomerization polymerization of alkenylcyclohexanes
• Intramolecular rearrangements of vinylidenecyclopropanes
• Cycloisomerization of cyclic and acyclic enynes

Additionally reactant involved in synthesis of biologically active molecules including:

• Dipeptidyl boronic acid proteasome inhibitors
• Substituted 1,3-dihydroindole-2-ones with antitumor effects
• Sulfur-free transition state nucleoside analog inhibitors of methylthioadenosine nucleosidase and phosphorylase

Safety Information

• pictograms: GHS02,GHS08,GHS05,GHS07
• signalword: Danger
• hcodes: H225,H302,H314,H335,H351
• pcodes: P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• target_organs: Respiratory system
• supp_hazards: EUH014,EUH019
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: -4.0 °F
• flash_point_c: -20 °C