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Sigma-Aldrich

Tetrakis(triphenylphosphine)palladium(0)

≥99.99% trace metals basis

Synonym(s):

Palladium-tetrakis(triphenylphosphine), Pd(PPh3)4

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About This Item

Linear Formula:
Pd[(C6H5)3P]4
CAS Number:
14221-01-3
Molecular Weight:
1155.56
Beilstein/REAXYS Number:
6704828
EC Number:
238-086-9
MDL number:
MFCD00010012
UNSPSC Code:
12161600
PubChem Substance ID:
329761903
NACRES:
NA.22

Quality Level

200

assay

≥99.99% trace metals basis

form

crystals

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

storage temp.

2-8°C

SMILES string

[Pd].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12

InChI

1S/4C18H15P.Pd/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;

InChI key

NFHFRUOZVGFOOS-UHFFFAOYSA-N

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pictograms

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GHS07

signalword

Warning

hcodes

H302

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
SHBP0402
SHBN3288
SHBM8447
SHBM2853
SHBL9011

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Wenhan Zhang et al.
Angewandte Chemie (International ed. in English), 53(34), 8980-8984 (2014-07-01)
tert-Butoxyacetylene is shown to undergo Sonogashira coupling with aryl iodides to yield aryl-substituted tert-butyl ynol ethers. These intermediates participate in a [1,5]-hydride shift, which results in the extrusion of isobutylene and the generation of aryl ketenes. The ketenes are trapped
Chanchal Chakraborty et al.
ACS applied materials & interfaces, 7(34), 19034-19042 (2015-08-19)
A platinum(II)-based, luminescent, metallo-supramolecular polymer (PolyPtL1) having an inherent dipole moment was synthesized via complexation of Pt(II) ions with an asymmetric ligand L1, containing terpyridyl and pyridyl moieties. The synthesized ligand and polymer were well characterized by various NMR techniques
Debabrata Jana et al.
Organic & biomolecular chemistry, 13(43), 10663-10674 (2015-09-09)
Four pyrene-vinyl-tetraphenylethylene based conjugated materials were synthesized and characterized by FT-IR, NMR, and mass spectroscopy. The photophysical (including absorption, fluorescence, and fluorescence lifetime) and aggregation properties in tetrahydrofuran were investigated. The photophysical and aggregation behavior depends on the spacer, substituent
Shouchun Yin et al.
Soft matter, 11(22), 4424-4429 (2015-05-01)
In this paper, a pyrene moiety is incorporated into a bolaamphiphile to form a novel molecule denoted PRB. Above the critical micelle concentration, PRB forms nanodisks in the aqueous solution. The addition of acetate ions induces a morphological change in
Haiyin Li et al.
Macromolecular bioscience, 14(10), 1361-1367 (2014-06-14)
Phospholipid monomer and aggregation-induced emission (AIE) dye-based dimers are incorporated via reversible addition-fragmentation transfer polymerization to afford cross-linked zwitterionic fluorescent copolymers. Such copolymers are prone to self-assembly into fluorescent polymeric nanoparticles (FPNs) in physiological solution due to their amphiphilic nature.

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