Skip to Content
MilliporeSigma
All Photos(2)

Key Documents

View All Documentation

683086

Sigma-Aldrich

[Ir(cod)(acac)]

Umicore

Synonym(s):

(Acetylacetonato)(1,5-cyclooctadiene)iridium(I), Acetylacetonato(1,5-cyclooctadiene)iridium(I), Ir(acac)(COD)

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Empirical Formula (Hill Notation):
C13H19IrO2
CAS Number:
12154-84-6
Molecular Weight:
399.51
MDL number:
MFCD08273779
UNSPSC Code:
12161600
PubChem Substance ID:
329760791
NACRES:
NA.22

form

crystals

reaction suitability

core: iridium
reagent type: catalyst

mp

150-155 °C (dec.)

SMILES string

CC(=O)\C=C(\C)O[Ir].C1CC=CCCC=C1

InChI

1S/C8H12.C5H8O2.Ir/c1-2-4-6-8-7-5-3-1;1-4(6)3-5(2)7;/h1-2,7-8H,3-6H2;3,6H,1-2H3;/q;;+1/p-1/b2-1-,8-7-;4-3-;

InChI key

JHNBKYKCHXHKET-DWVXZKBMSA-M

Looking for similar products? Visit Product Comparison Guide

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Precursor for Iridium complexes and catalysts

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCQ1186
MKCL9311
MKCL0428
MKBW9309V
MKBQ6582V

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

G Sava et al.
Chemico-biological interactions, 45(1), 1-6 (1983-07-01)
The effects of square planar rhodium, [RhacacCOD]o and iridium, [IracacCOD]o complexes and of octahedral ruthenium, [cis-RuCl2 (DMSO)4]o complex have been examined in comparison with cis-dichlorodiammino platinum(II) (cis-PDD). The toxicity in BDF1 mice varies widely and decreasing LD50-values, ranging from 0.94

Articles

Umicore Precatalysts

We are happy to offer a series of precatalysts for asymmetric catalysis and Pd based cross coupling catalysis. Our partnership with Umicore allows us to offer a portfolio of metal complexes with batch-to-batch consistency for a plethora of catalytic reactions.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service