Skip to Content
MilliporeSigma
All Photos(1)

Key Documents

429147

Sigma-Aldrich

(Acetylacetonato)dicarbonyliridium(I)

Synonym(s):

Dicarbonyl(2,4-pentanedionato)iridium

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
Ir(acac)(CO2)
CAS Number:
Molecular Weight:
347.35
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22

Quality Level

reaction suitability

core: iridium
reagent type: catalyst

SMILES string

[C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Ir]

InChI

1S/C5H8O2.2CO.Ir/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;

InChI key

DFIAYCFHPDOZLK-FGSKAQBVSA-M

Related Categories

Application

Catalyst for isomerization and anti-Markovnikov arylation of olefins

Reactant for:
  • Oxidative addition of perfluoroalkyl iodides
  • Synthesis of iridium heterocycles
  • Scaffolding of iridium complexes
  • Metal carbonyl cluster synthesis
  • Mixed-bridged bimetallic d8 complex synthesis

pictograms

Exclamation markHealth hazard

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service