Skip to Content
MilliporeSigma
All Photos(1)

Key Documents

497517

Sigma-Aldrich

Benzylzinc bromide solution

0.5 M in THF

Synonym(s):

Benzylbromozinc, Benzylzinc(II) bromide, Bromo(phenylmethyl)zinc

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
C6H5CH2ZnBr
CAS Number:
Molecular Weight:
236.42
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

Quality Level

concentration

0.5 M in THF

density

0.978 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

Br[Zn]Cc1ccccc1

InChI

1S/C7H7.BrH.Zn/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1

InChI key

OQPRTUBCROVGHA-UHFFFAOYSA-M

Application

Benzylzinc bromide solution can be used as a nucleophile for the Mannich-type synthesis of 1,2-diarylethylpiperazines. It can also undergo C−C cross coupling reactions with aryl halides.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

1.0 °F - closed cup

flash_point_c

-17.22 °C - closed cup


Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Straightforward three-component synthesis of diarylmethylpiperazines and 1, 2-diarylethylpiperazines.
Sengmany S, et al.
Tetrahedron, 63(18), 3672-3681 (2007)
Nickel Complexes Modified by O, N, O?-Ligands as Synthons for the Straightforward Synthesis of Highly Efficient Precatalysts for C-C Bond Formation.
Someya CI, et al.
Asian Journal of Organic Chemistry, 1(4), 322-326 (2012)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service