656984
reaction type: Grignard Reaction
1.3 M in THF
0.951 g/mL at 25 °C
[Li]Cl.CC(C)[Mg]Cl
1S/C3H7.2ClH.Li.Mg/c1-3-2;;;;/h3H,1-2H3;2*1H;;/q;;;2*+1/p-2
CWTUREABAILGIK-UHFFFAOYSA-L
Danger
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
Respiratory system
4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGK 3
1.4 °F
-17 °C
dust mask type N95 (US), Eyeshields, Gloves
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Selective Metalations using i-PrMgCl·LiCl and s-BuMgCl·LiCl
Transformative reagents for selective metalation, deprotonation and nucleophilic additions have allowed for unprecedented selective converstions to reactive intermediates within a molecule which contains sensative functionalities under mild reactions.
We present an article concerning Reagents for Selective Metalation, Deprotonation, and 1,2-Additions.
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