439606
Diallyl N,N-diisopropylphosphoramidite
Synonym(s):
N,N-Bis(1-methylethyl)phosphoramidous acid di-2-propenyl ester, Diallyloxy(diisopropylamino)phosphine
About This Item
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form
liquid
Quality Level
refractive index
n20/D 1.456 (lit.)
bp
130 °C (lit.)
density
0.928 g/mL at 25 °C (lit.)
functional group
amine
storage temp.
2-8°C
SMILES string
CC(C)N(C(C)C)P(OCC=C)OCC=C
InChI
1S/C12H24NO2P/c1-7-9-14-16(15-10-8-2)13(11(3)4)12(5)6/h7-8,11-12H,1-2,9-10H2,3-6H3
InChI key
QBLCHHSGJTUNSJ-UHFFFAOYSA-N
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Application
- Preparation of peptide substrates.
- Preparation of rhodamine dyes with phosphorylated CH2OH sites.
- Synthesis of 3-[4-(bis-allyloxy-phosphoryloxy)-2(R)-hydroxy-3,3-dimethyl-butyrylamino]-thiopropionic acid-S-propylester.
- Selective orally active S1P1 agonists
- Water-soluble prodrugs of triazole CS-758 with antifungal activity
- Fostriecin analogs as antitumor agents
Reactant involved in:
- Phosphitylation of alcohols
- Deallylation for the synthesis of nucleoside phosphoramidite
- Posphitylation and stereoselective Pudovik rearrangement
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
3 - Flammable liquids
wgk_germany
WGK 3
flash_point_f
89.6 °F - closed cup
flash_point_c
32 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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