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Sigma-Aldrich

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate hydrate

97%

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About This Item

Empirical Formula (Hill Notation):
C16H24BF4Rh · xH2O
CAS Number:
207124-65-0
Molecular Weight:
406.07 (anhydrous basis)
MDL number:
MFCD00167214
UNSPSC Code:
12161600
PubChem Substance ID:
24860274
NACRES:
NA.22

assay

97%

reaction suitability

core: rhodium
reagent type: catalyst

mp

165 °C (dec.) (lit.)

SMILES string

O.[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2

InChI

1S/2C8H12.BF4.H2O.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)5;;/h2*1-2,7-8H,3-6H2;;1H2;/q;;-1;;+1/b2*2-1-,8-7-;;;

InChI key

NYMNQNLSUITCLM-DIURZKMRSA-N

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pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKBJ9590V
MKBD6317V
MKBD6317
08313BE
16603LS

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Articles

Alkyne Hydrosilylation

Vinyl-metal reagents play a pivotal role in organic synthesis. Among the vinyl-metal reagents available, silicon-based reagents are of increasing importance. This is largely due to their low cost, minimal toxicity, ease of handling, and the simplicity of byproduct removal.

Hydrosilylation Catalyst

A Highly Efficient Hydrosilylation Catalyst, sigma-aldrich is pleased to offer [Cp*Ru(MeCN)3]PF6, as well as a number of other catalysts for hydrosilylation.

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